The electronic structure of semimagnetic semiconductor ternary alloys Cd,_,M,Se (M = Mn, Fe, CO) crystals was investigated by photoemission. The ground state of impurity level of Fe 3d6 and CO 3d7 were found to determine the position of the edge of the valence band of the ternary alloys crystals Cd, -,Fe,Se and Cd,-,Co,Se. The core level Se 3d spectra measured for Cd, -,Fe,Se crystals with different composition x correspond to the apperance of local structure in the crystal. The valence band density of states distribution was estimated for MnSe, FeSe and CoSe with CdSe structure as a difference between valence band density of states distribution for Cd,-,Mn,Se, Cd,-,Fe,Se or Cd,-,Co,Se respectively and CdSe.