2001
DOI: 10.1063/1.1419034
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Lithium storage in polymerized carbon nitride nanobells

Abstract: Polymerized carbon nitride nanobells (CNNBs) have been intercalated by a large amount of Li ions using an electrochemical method. Li nanocrystals are observed on the inside surface of CNNB walls, which is direct evidence that a Li nanocrystal can exist at the micropore structure at a heavy intercalating level. Graphene layers are expanded and become partly disordered by Li intercalation, while after deintercalation, they are reordered to a certain degree, and Li nanocrystals disappear. The samples show a rever… Show more

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Cited by 81 publications
(40 citation statements)
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“…As shown in Figure 3 d). [ 24 ] A highresolution TEM image of the fi ne microstructure shows that these nanosheets have sharp edges and a turbostratic structure ( Figure S10, Supporting Information). Such a 3D interconnected network of porous nanosheets containing many junctions and the open pores provide a good combination of infi ltration rate and surface area, [ 25 ] and are also favorable for mass transfer and charge separation.…”
Section: Doi: 101002/adma201502057mentioning
confidence: 97%
“…As shown in Figure 3 d). [ 24 ] A highresolution TEM image of the fi ne microstructure shows that these nanosheets have sharp edges and a turbostratic structure ( Figure S10, Supporting Information). Such a 3D interconnected network of porous nanosheets containing many junctions and the open pores provide a good combination of infi ltration rate and surface area, [ 25 ] and are also favorable for mass transfer and charge separation.…”
Section: Doi: 101002/adma201502057mentioning
confidence: 97%
“…Hence the stripes in the samples were ascribed to metallic lithium nanocrystallites. [30,31] It should be mentioned that outside the tube wall, there is a uniform amorphous film with a thickness of about 5-7 nm. That is the so called solid electrolyte interphase (SEI) layer formed by the reduction of the electrolyte.…”
mentioning
confidence: 99%
“…Light emission has been reported from carbon nanotubes (CNTs) as nanometersized filaments [1,2] and from boron carbonitride fibres. [3] CNTs have also been used as a carrier by doping Eu or Eu compounds on the nanotube external surfaces, [4,5] but in these cases CNTs are not involved in the light emission. Wide-bandgap semiconductors doped with rare-earth ions are considered as a new type of luminescent material, combining special wide-bandgap semiconducting properties with the rare-earth luminescence feature.…”
mentioning
confidence: 99%