Lithium plating detection using dynamic electrochemical impedance spectroscopy in lithium-ion batteries

Koseoglou, Markos; Tsioumas, Evangelos; Ferentinou, Dimitra; Jabbour, Nikolaos; Papagiannis, Dimitrios; Mademlis, Christos

doi:10.1016/j.jpowsour.2021.230508

Cited by 47 publications

(16 citation statements)

References 55 publications

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“…57,58 Electrical impedance spectroscopy studies have shown that typical activation energies for lithium plating on different electrode materials (including graphite, lithium nickel cobalt aluminate and lithium iron phosphate) can vary from $0.50 eV to 0.75 eV, which is an order of magnitude lower than the energy imparted by atoms during lithium sputtering. [59][60][61] For ebeam evaporation with higher evaporation rates, the vapour becomes "less ideal", leading to higher energy Li deposition, but this is still expected to be well below that of sputtering.…”

Section: Faraday Discussion Papermentioning

confidence: 99%

Gently does it!: in situ preparation of alkali metal–solid electrolyte interfaces for photoelectron spectroscopy

et al. 2022

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Section: Faraday Discussion Papermentioning

confidence: 99%

Gently does it!: in situ preparation of alkali metal–solid electrolyte interfaces for photoelectron spectroscopy

et al. 2022

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“…Excitation signals, output responses, advantages, and disadvantages of different impedance techniques: (a) classical EIS (reprinted with permission from ref . Copyright 2021 Springer Nature); (b) linear DEIS (reprinted with permission from ref . Copyright 2021 Elsevier.…”

Section: Eis Measurementmentioning

confidence: 99%

Application of Electrochemical Impedance Spectroscopy to Degradation and Aging Research of Lithium-Ion Batteries

Peng

Wei³

et al. 2023

J. Phys. Chem. C

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An in-depth understanding of battery degradation and aging in-Operando not only plays a vital role in the design of battery managing systems but also helps to ensure safe use and manufacturing optimization of lithium-ion batteries (LIBs) in large-scale applications. Electrochemical impedance spectroscopy (EIS) is a nondestructive method which unravels electrode kinetic processes inside the batteries in different time domains, including charge-transfer reactions, interfacial evolutions, and mass diffusions. It has become a powerful diagnosis and pre/prognosis tool in battery aging research, as it provides important insight into the changes of internal electrochemical processes by correlating the impedance evolution to degradation mechanisms. This review gives a critical overview on rapidly developing impedance techniques for degradation and aging investigation of Li-ion batteries. The EIS variations of LIBs at different aging conditions of calendar aging and accelerated aging are systematically summarized. In addition, the working principles, data validation, and modeling methods, including equivalent circuit model (ECM), distribution of relaxation times (DRT), and transmission line model (TLM), of classical EIS and dynamic EIS are elaborately concluded. Finally, the challenges and perspectives of further application of EIS in the aging research of LIBs are presented.

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“…Through advanced characterization techniques, the mechanism of battery degradation during fast‐charging can be explored, especially the dynamic analysis of Li deposition process, Li + migration paths and transport kinetics, and even quantitative studies. Koseoglou's team [83] proposed a Li plating detection method based on dynamic electrochemical impedance spectroscopy (DEIS) technique for LIBs impedance analysis, which can detect the onset of Li plating in real time by monitoring the interface impedance. Specifically, the current signal from DEIS is superimposed on the charging current to analyze the battery impedance without influencing and interrupting the charging process.…”

Section: Theoretical and Experimental Research Techniquesmentioning

confidence: 99%

Fast‐Charging Strategies for Lithium‐Ion Batteries: Advances and Perspectives

Zhao

Song

2022

ChemPlusChem

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Rapid development of high-energy-density lithium-ion batteries (LIBs) enables the sufficient driving range of electric vehicles (EVs). However, the slow charging speed restricts the popularization of EVs. Commitment to fast-charging research is considered to be the key to advance the EVs strategy. This Review discusses the kinetic factors limiting the fast-charging capability at the material aspects, and summarizes the recent research strategies to achieve fast-charging performance of high-energy-density LIBs through electrode engineering, electrolyte design, and interface optimization. The increasingly important role of computational tools and advanced characterization techniques in fundamentally understanding the failure mechanism of LIBs is emphasized, and the analysis of the thermal runaway problem in the fast-charging process and the corresponding thermal optimization scheme is also involved to give the guidance for the more rational battery design. In view of these factors and strategies, some future perspectives for realizing high-performance fast-charging LIBs are proposed, which are expected to facilitate the large-scale application of fast-charging LIBs in EVs.

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Lithium plating detection using dynamic electrochemical impedance spectroscopy in lithium-ion batteries

Cited by 47 publications

References 55 publications

Gently does it!: in situ preparation of alkali metal–solid electrolyte interfaces for photoelectron spectroscopy

Gently does it!: in situ preparation of alkali metal–solid electrolyte interfaces for photoelectron spectroscopy

Application of Electrochemical Impedance Spectroscopy to Degradation and Aging Research of Lithium-Ion Batteries

Fast‐Charging Strategies for Lithium‐Ion Batteries: Advances and Perspectives

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