Lithium

Schäfer, Ulrich

doi:10.1002/9783527619634.ch23a

Elements and Their Compounds in the Environment 2004

DOI: 10.1002/9783527619634.ch23a

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Lithium

Ulrich Schäfer¹

Abstract: Elements and their Compounds in the Environment. 2nd Edition. Edited by E. Merian, M. Anke, M. Ihnat, M. Stoeppler

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Cited by 4 publications

References 58 publications

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Lithium Sorption/Desorption in Some Alkaline Soils: Modeling of the Kinetics Behavior

Elbana

Osman

2023

Water Air Soil Pollut

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Global concern over lithium (Li) in the environment has significantly increased due to its widespread uses. However, the literature review on Li kinetics in alkaline soils is scant. Hence, batch experiments were conducted to quantify and simulate the retention and release of Li in sandy and sandy clay loam alkaline soils. Sorption isotherms were fitted using Freundlich and Langmuir equations. Second-order two site (SOTS) and multi-reaction (MRM) models were applied to simulate sorption/desorption kinetic data. Results revealed the nonlinear behavior of Li sorption isotherms in both studied soils. The maximum sorption capacity (Smax) for the sandy clay loam soil (1268.6 mg kg−1) was three-fold higher than the sandy soil (368.9 mg kg−1) after 7 days of equilibration. The sandy soil and sandy clay loam soils exhibited distinctive kinetic Li sorption/desorption behavior. MRM and SOTS models described Li sorption/desorption kinetic well by considering the reversible and irreversible reactions in alkaline soils. Results indicate that sandy soil exhibits a time-dependent sorption behavior and a restricted desorption kinetic. In contrast, the sandy clay loam exhibited a limited time-dependent Li sorption, while the kinetic behavior was observed during the desorption reaction. Graphical abstract

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Lithium Sorption/Desorption in Some Alkaline Soils: Modeling of the Kinetics Behavior

Elbana

Osman

2023

Water Air Soil Pollut

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Enrichment of lithium in lettuce plants through agronomic biofortification

Silva

Faria

Alexandrino

et al. 2019

Journal of Plant Nutrition

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Elemental Mapping of Lithium Diffusion in Doped Plant Leaves Using Laser-Induced Breakdown Spectroscopy (LIBS)

et al. 2019

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Mapping of element distributions and diffusion processes in plant tissue has great significance for understanding the systematic uptake, transport, and accumulation of nutrients and harmful elements in plants, and for studying the interaction between plants and the environment. In this work, we used laser-induced breakdown spectroscopy (LIBS) to study the elemental accumulation of Li and its diffusion in plant leaves. The spatially resolved information that LIBS offers, combined with its high sensitivity to light elements make this technology highly advantageous for the analysis of Li. Laser-induced breakdown spectroscopy mapping of Li-doped leaf samples is used to directly visualize the diffusion of Li in the plant leaf and study its distribution as a function of LiCl solution exposure time. Our findings demonstrate that diffusion of Li in plant leaves occurs though their veins (i.e., bundles of vascular tissue) and that Li concentration decreases as we move away from the LiCl exposure site. These results underline the importance of veins in transportation of toxic elements in plants, and mapping of their distribution can be instrumental in the development of possible remediation approaches for managing Li toxicity.

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Lithium

Abstract: Elements and their Compounds in the Environment. 2nd Edition. Edited by E. Merian, M. Anke, M. Ihnat, M. Stoeppler

Cited by 4 publications

References 58 publications

Lithium Sorption/Desorption in Some Alkaline Soils: Modeling of the Kinetics Behavior

Lithium Sorption/Desorption in Some Alkaline Soils: Modeling of the Kinetics Behavior

Enrichment of lithium in lettuce plants through agronomic biofortification

Elemental Mapping of Lithium Diffusion in Doped Plant Leaves Using Laser-Induced Breakdown Spectroscopy (LIBS)

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