Lithiations and Grignard Reactions on Pyrimidine and Quinazoline

Kolarovič, Andrej

doi:10.1007/7081_2012_94

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Visible‐Light‐Triggered, Metal‐ and Photocatalyst‐Free Acylation of N‐Heterocycles

2018

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A photoinduced acylation of N-heterocycles is explored. This visible-light triggered reaction occurs not only under extremely mild reaction conditions, but also does not require the presence of a photosensitizer. The mechanistic studies suggest formation of EDA complexes prompt to harness the energy from visible-light. Compatibility with a large panel of a-keto acids as acyl precursors and an array of Nheterocycles clearly showcase the synthetic potential of this handy and green acylation protocol.

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