Lilac ceramic pigments based on Ba 0.5 Sr 0.5 Zn 2−x Ni x Si 2 O 7 solid solutions

Thieme, Christian; Waurischk, Tina; Lin, Changgui

doi:10.1016/j.ceramint.2016.05.082

Cited by 8 publications

(5 citation statements)

References 24 publications

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“…It is important to note that a magenta color for a nickel compound is very rare. The recently reported Ba 0.5 Sr 0.5 Zn 2− x Ni x Si 2 O 7 is the only other example in which Ni imparts an unusual lilac color (related to magenta) …”

Section: Resultsmentioning

confidence: 99%

“…The recently reported Ba 0.5 Sr 0.5 Zn 2Àx Ni x Si 2 O 7 is the only other example in which Ni impartsa nu nusuall ilac color (relatedt o magenta). [21] Divalent coppers ubstitution in a-LiZnBO 3 , a-LiZn 1Àx Cu II x BO 3 (0 < x 0.10), results in as ingle phase only up to x = 0.10. The copper-substitutedc ompounds are violet in color (Figure 9, inset).…”

Section: Divalent Tm Ion Substitutionmentioning

confidence: 99%

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Developing Intense Blue and Magenta Colors in α‐LiZnBO₃: The Role of 3d‐Metal Substitution and Coordination

Subramani

Reddy

Natarajan

et al. 2016

Chemistry An Asian Journal

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Section: Resultsmentioning

confidence: 99%

Section: Divalent Tm Ion Substitutionmentioning

confidence: 99%

Developing Intense Blue and Magenta Colors in α‐LiZnBO₃: The Role of 3d‐Metal Substitution and Coordination

Subramani

Reddy

Natarajan

et al. 2016

Chemistry An Asian Journal

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“…Dalam teknologi yang memerlukan pemeriksaan secara visual, kod warna merupakan kaedah yang dapat memberikan maklumat dengan cepat serta warna merupakan kaedah yang paling mudah dalam menyampaikan struktur dan bentuk bahan. Warna telah digunakan secara meluas dalam industri kaca dan seramik (Boschetti et al 2016;Holgado et al 2016;Jovaní et al 2016;Kim & Kim 2016;Mantovani et al 2015;Möncke et al 2014;Nor et al 2016;Skowroński et al 2014;Thieme et al 2016). Terdapat kajian yang cuba untuk mewarnakan sambungan pempaterian (King & Gulino 1998;Zeng et al 2011) untuk pelbagai aplikasi (Jiang et al 2007;Kim 2000;Kim & Cho 1995).…”

Section: Pengenalanunclassified

Kesan Pigmen Pewarna terhadap Pertumbuhan Sebatian antara Logam Sambungan Pateri Sn-3.0Ag-0.5Cu

Jalar¹,

Bakar

Ismail

et al. 2018

JSM

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Pewarnaan pes pateri membuka suatu ruang kepada keperluan dalam teknologi untuk proses pengenalpastian, penandaan, piawaian, pengujian dan penilaian terhadap antarasambungan pes pateri. Dua jenis pigmen pewarna iaitu hijau (G) dan bercahaya dalam gelap (GD) digunakan untuk mengkaji kesan pewarnaan sambungan pateri ke atas kestabilan antarasambungan pateri Sn-3.0Ag-0.5Cu (SAC 305). Pes pateri tanpa warna digunakan sebagai sampel kawalan untuk membandingkan keputusan kajian. Uji kaji penuaan sesuhu digunakan untuk melihat perubahan pertumbuhan sebatian antara logam (IMC). Pigmen pewarna GD dengan peratusan sebanyak 5% telah menunjukkan kestabilan pertumbuhan IMC dengan perubahan pertumbuhan yang paling rendah iaitu sebanyak 5.6 µm bagi sambungan pateri yang berwarna berbanding dengan peratusan pigmen pewarna yang lebih tinggi dengan perubahan pertumbuhan IMC sehingga 9 µm selepas didedahkan kepada penuaan sesuhu pada 150°C selama 1000 jam. Walau bagaimanapun, kestabilan pertumbuhan IMC dengan penggunaan pes pateri berwarna adalah lebih rendah berbanding dengan pes pateri tidak berwarna. Maka penambahan pigmen pewarna hendaklah dipertimbangkan dengan mengambil kira kestabilan mikrostruktur dan pertumbuhan lapisan IMC supaya tidak menjejaskan kualiti dan kebolehharapan sesuatu sambungan pateri.

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“…22 In the case of Ni 25 and so on. When Ni 2+ resides in distorted tetrahedral positions, it exhibits different colors such as magenta and lilac, 26,27 as shown in Figure 2.…”

Section: Introductionmentioning

confidence: 99%

“…In the case of Ni 2+ , previous research has effectively produced various blue hues by Ni 2+ doping in regular tetrahedral coordination in structures such as CaAl 12 O 19 , BaAl 12 O 19 , MgAl 2 O 4 , and so on. When Ni 2+ resides in distorted tetrahedral positions, it exhibits different colors such as magenta and lilac, , as shown in Figure . However, these pigments have the problems of complicated preparation, expensive price, or poor color performance, and an intense blue hue has not yet been achieved by Ni 2+ into tetrahedral coordination.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and Optical Properties Based on Ni-Doped Zn₂SiO₄ Blue Pigments with High-NIR Reflectance

Wang,

et al. 2024

ACS Sustainable Chem. Eng.

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The severe urban heat island effect emphasizes the heightened importance of reducing building energy consumption. Cool pigments with higher near-infrared reflectivity contribute to the overall coating performance of the building. In this work, a novel intense blue pigment with superior infrared reflectance based on Ni-doped Zn 2 SiO 4 was successfully synthesized via the simple solid-state method. The crystal structure, oxidation states, and optical properties are analyzed. The oxidation state of Ni was confirmed to be +2 using magnetic analysis and XPS. The intense blue color exhibited by the solid solution is due to the 3 T 1 ( 3 F) → 3 T 1 ( 3 P) transition of Ni 2+ at the tetrahedral sites. UV−vis−NIR spectra demonstrate that this pigment exhibits superior near-infrared reflectance compared to cobalt blue in the range of 900−1700 nm, indicating its potential application in the realm of building energy conservation.

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Lilac ceramic pigments based on Ba 0.5 Sr 0.5 Zn 2−x Ni x Si 2 O 7 solid solutions

Cited by 8 publications

References 24 publications

Developing Intense Blue and Magenta Colors in α‐LiZnBO₃: The Role of 3d‐Metal Substitution and Coordination

Developing Intense Blue and Magenta Colors in α‐LiZnBO₃: The Role of 3d‐Metal Substitution and Coordination

Kesan Pigmen Pewarna terhadap Pertumbuhan Sebatian antara Logam Sambungan Pateri Sn-3.0Ag-0.5Cu

Synthesis and Optical Properties Based on Ni-Doped Zn₂SiO₄ Blue Pigments with High-NIR Reflectance

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Lilac ceramic pigments based on Ba 0.5 Sr 0.5 Zn 2−x Ni x Si 2 O 7 solid solutions

Cited by 8 publications

References 24 publications

Developing Intense Blue and Magenta Colors in α‐LiZnBO3: The Role of 3d‐Metal Substitution and Coordination

Developing Intense Blue and Magenta Colors in α‐LiZnBO3: The Role of 3d‐Metal Substitution and Coordination

Kesan Pigmen Pewarna terhadap Pertumbuhan Sebatian antara Logam Sambungan Pateri Sn-3.0Ag-0.5Cu

Synthesis and Optical Properties Based on Ni-Doped Zn2SiO4 Blue Pigments with High-NIR Reflectance

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Product

Resources

About

Developing Intense Blue and Magenta Colors in α‐LiZnBO₃: The Role of 3d‐Metal Substitution and Coordination

Developing Intense Blue and Magenta Colors in α‐LiZnBO₃: The Role of 3d‐Metal Substitution and Coordination

Synthesis and Optical Properties Based on Ni-Doped Zn₂SiO₄ Blue Pigments with High-NIR Reflectance