Abstract:Remote detection of chemical and biological warfare agents and toxic gases in the atmosphere is of current interest to both the military and civilian agencies. Out of all currently available techniques, no single technique provides efficient detection against such threats at significant standoff distances. Light detection and ranging (LIDAR) technologies, based on the transmission of laser pulses and analysis of the return signals, have demonstrated impressive capabilities in remote detection of such toxic che… Show more
“…The concentration of the target gas can be measured by detecting the difference between the returned signals of the two lasers [16]. Assuming the transmitted power is P t , the overall system efficiency is η, the telescope receiving area is A, the distance of the hard target is R, the reflectivity of the hard target is ρ, the absorption cross-sections of λ on and λ off are σ on and σ off , the atmospheric attenuation coefficient is α and the number concentration of the molecule is N(R), then the energy P received by the detector can be expressed as [17][18][19]:…”
Developments in mid-infrared Differential Absorption Lidar (DIAL), for gas remote sensing, have received a significant amount of research in recent years. In this paper, a high repetition rate tunable mid-infrared DIAL, mounted on a mobile platform, has been built for long range remote detection of gas plumes. The lidar uses a solid-state tunable optical parametric oscillator laser, which can emit laser pulse with repetition rate of 500 Hz and between the band from 2.5 μm to 4 μm. A monitoring channel has been used to record the laser energy in real-time and correct signals. Convolution correction technology has also been incorporated to choose the laser wavelengths. Taking NO2 and SO2 as examples, lidar system calibration experiment and open field observation experiment have been carried out. The observation results show that the minimum detection sensitivity of NO2 and SO2 can reach 0.07 mg/m3, and 0.31 mg/m3, respectively. The effective temporal resolution can reach second level for the high repetition rate of the laser, which demonstrates that the system can be used for the real-time remote sensing of atmospheric pollution gas.
“…The concentration of the target gas can be measured by detecting the difference between the returned signals of the two lasers [16]. Assuming the transmitted power is P t , the overall system efficiency is η, the telescope receiving area is A, the distance of the hard target is R, the reflectivity of the hard target is ρ, the absorption cross-sections of λ on and λ off are σ on and σ off , the atmospheric attenuation coefficient is α and the number concentration of the molecule is N(R), then the energy P received by the detector can be expressed as [17][18][19]:…”
Developments in mid-infrared Differential Absorption Lidar (DIAL), for gas remote sensing, have received a significant amount of research in recent years. In this paper, a high repetition rate tunable mid-infrared DIAL, mounted on a mobile platform, has been built for long range remote detection of gas plumes. The lidar uses a solid-state tunable optical parametric oscillator laser, which can emit laser pulse with repetition rate of 500 Hz and between the band from 2.5 μm to 4 μm. A monitoring channel has been used to record the laser energy in real-time and correct signals. Convolution correction technology has also been incorporated to choose the laser wavelengths. Taking NO2 and SO2 as examples, lidar system calibration experiment and open field observation experiment have been carried out. The observation results show that the minimum detection sensitivity of NO2 and SO2 can reach 0.07 mg/m3, and 0.31 mg/m3, respectively. The effective temporal resolution can reach second level for the high repetition rate of the laser, which demonstrates that the system can be used for the real-time remote sensing of atmospheric pollution gas.
“…In terms of assessing the war's damage caused to the environment, remote sensing data have shown the ability in detecting and indicating the impact of war on the environment For example, Veerabuthiran in 2011 used the LIDAR data for detection of biological warfare agents and toxic gases in the atmosphere [58]. Reuveny in 2010showed in his study the effects of warfare on the environment [59].…”
Section: Remote Sensing Rule In Studying the Conflictsmentioning
“…Additionally, the detection of the precursors and degradation products of these materials can be equally important [3]. Existing technology has shown that these devices can effectively detect such analytes, but requires high-tech, expensive, and large instrumentation, which makes them less than ideal for field applications [4,5,6,7].…”
Chemical warfare agents pose significant threats in the 21st century, especially for armed forces. A colorimetric detection array was developed to identify warfare mimics, including mustard gas and nerve agents. In total, 188 sensors were screened to determine the best sensor performance, in order to identify warfare mimics 2-chloro ethyl ethylsulfide, 2-2′-thiodiethanol, trifluoroacetic acid, methylphosphonic acid, dimethylphosphite, diethylcyanophosphonate, and diethyl (methylthiomethyl)phosphonate. The highest loadings in the principle component analysis (PCA) plots were used to identify the sensors that were most effective in analyzing the RGB data to classify the warfare mimics. The dataset was reduced to only twelve sensors, and PCA results gave comparable results as the large data did, demonstrating that only twelve sensors are needed to classify the warfare mimics.
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