Li2Ca2Si2O7: Structural, spectroscopic and computational studies on a sorosilicate

Kahlenberg, Volker; Brunello, Emanuele; Hejny, Clivia; Krüger, Hannes; Schmidmair, Daniela; Tribus, Martina; Többens, Daniel M.

doi:10.1016/j.jssc.2014.12.009

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Cited by 7 publications

(1 citation statement)

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“…The Si-O bond lengths are distributed over the range 1.46-1.74Å with the longest bond to the bridging O b as found in earlier studies of other pyrosilicates. 26 The Mn ions assume two distinct crystallographic positions within each Mn layer: tetrahedral in a corner-sharing conguration, and square-pyramidal (Mn-O < 2.5Å) with both corner and edge-sharing connectivity to their neighbouring coordination polyhedra (Fig. 1 inset).…”

Section: àmentioning

confidence: 99%

Manganese pyrosilicates as novel positive electrode materials for Na-ion batteries

Renman

Valvo

Tai

et al. 2018

Sustainable Energy Fuels

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Section: àmentioning

confidence: 99%

Manganese pyrosilicates as novel positive electrode materials for Na-ion batteries

Renman

Valvo

Tai

et al. 2018

Sustainable Energy Fuels

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ChemInform Abstract: Li₂Ca₂Si₂O₇: Structural, Spectroscopic and Computational Studies on a Sorosilicate.

et al. 2015

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Li 2Ca2Si2O7: Structural, Spectroscopic and Computational Studies on a Sorosilicate. -Single crystals of the title compound are prepared from stoichiometric mixtures of Li 2CO3, CaCO3, and SiO2 (Pt crucible, 900 C, 12 h). Li2Ca2Si2O7 crystallizes in the hexagonal space group P6122 with Z = 6 (single crystal XRD) and belongs to the group of pyrosilicates containing [Si 2O7] groups. Lithium and calcium cations are incorporated between the silicate dimers and are coordinated by four and six nearest oxygen neighbors, respectively. The compound is further characterized by Raman spectroscopy and DFT calculations. -(KAHLENBERG*, V.; BRUNELLO, E.; HEJNY, C.; KRUEGER, H.; SCHMIDMAIR, D.; TRIBUS, M.; TOEBBENS, D. M.; J. Solid State Chem. 225 (2015) 155-167, http://dx.

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Insight into a concentration-sensitive red-emitting phosphor Li2Ca4Si4O13:Eu3+ for multifunctional applications: Crystal structure, electronic structure and luminescent properties

Zhao

Zheng

et al. 2020

Ceramics International

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Li2Ca2Si2O7: Structural, spectroscopic and computational studies on a sorosilicate

Cited by 7 publications

References 42 publications

Manganese pyrosilicates as novel positive electrode materials for Na-ion batteries

Manganese pyrosilicates as novel positive electrode materials for Na-ion batteries

ChemInform Abstract: Li₂Ca₂Si₂O₇: Structural, Spectroscopic and Computational Studies on a Sorosilicate.

Insight into a concentration-sensitive red-emitting phosphor Li2Ca4Si4O13:Eu3+ for multifunctional applications: Crystal structure, electronic structure and luminescent properties

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Li2Ca2Si2O7: Structural, spectroscopic and computational studies on a sorosilicate

Cited by 7 publications

References 42 publications

Manganese pyrosilicates as novel positive electrode materials for Na-ion batteries

Manganese pyrosilicates as novel positive electrode materials for Na-ion batteries

ChemInform Abstract: Li2Ca2Si2O7: Structural, Spectroscopic and Computational Studies on a Sorosilicate.

Insight into a concentration-sensitive red-emitting phosphor Li2Ca4Si4O13:Eu3+ for multifunctional applications: Crystal structure, electronic structure and luminescent properties

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Product

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About

ChemInform Abstract: Li₂Ca₂Si₂O₇: Structural, Spectroscopic and Computational Studies on a Sorosilicate.