Lead Zirconium Titanate Films and Devices Made by a Low- Temperature Solution-Based Process

Abstract

As the most important multifunctional oxide material, lead zirconium titanate (PZT) has a diverse range of applications such as piezo actuators, ferroelectric nonvolatile memories, sensors, and transducers due to its excellent structural and electrical properties. However, it generally requires a high annealing temperature (above 600°C) to attain the desired properties, which hinders the integration of PZT with silicon-based Complementary Metal Oxide Semiconductor (CMOS). Therefore, the fabrication of PZT films by a chemical solution deposition (CSD) at temperatures compatible with Si-CMOS technology or even with polymeric substrate for flexible electronics would be of high technological interest. So far, different strategies to decrease the crystallization temperature of CSD-derived PZT films have been studied. This chapter presents a critical review on the low-temperature solution-processed PZT films and devices, and addresses challenges for fundamental understanding and practical integration of multifunctional PZT in devices. In the first part, recent advances in fabrication of CSD-derived PZT films at a low temperature are thoroughly reviewed. The second part discusses various techniques for patterning PZT into micro-nano-sized patterns. Lastly, some potential applications of the low-temperature CSD-derived PZT films and devices are demonstrated.

Direct processing of PbZr0.53Ti0.47O3 films on glass and polymeric substrates

“…[1] However, when it comes to incorporating ferroelectric thin films into complementary metal-oxide-semiconductor (CMOS) processes, temperature incompatibility is a major challenge. High-quality ferroelectric thin films require crystallization temperatures above 600 • C [2], but CMOS processes cannot withstand temperature above 400 • C, mainly due to the use of metallic circuit materials, as well as modification of the dopant profiles within the various layers, resulting in loss of functionalities. [3] Moreover, demand for transparent touching panels and peel-and-stick sensors [4,5,6,7] has greatly increased in recent years.…”