Stimulated rotational Raman scattering (SRRS) at multiwavelength pumped by TEA CO 2 laser was demonstrated in this paper. Raman mediums were cooled by liquid N 2 and a multiple pass cell (MPC) with 25 passes was designed and used. When the para H2 was pumped by single longitudinal mode (SLM) circular polarized TEA CO 2 laser on 10P (20), 9P (20), and 10R (20), 50 mJ 16.95 µm, 350 mJ 14.44 µm, and 536 mJ 16.9 µm radiations were obtained, corresponding to energy conversion efficiency of 1.2, 11.7, and 13.4%, respectively. When the ortho D 2 was pumped by CO 2 laser on 10R(18), 108 mJ 12.57 µm Raman laser was obtained with energy conversion efficiency of 2.9%.