Displays and indicators are an integral
component of everyday electronics.
However, the short lifecycle of most applications is currently contributing
to the unsustainable growth of electronic waste. In this work, we
utilize ecofriendly materials in combination with sustainable processing
techniques to fabricate inkjet-printed, ecofriendly dual-mode displays
(DMDs). These displays can be used in a reflective mode or an emissive
mode by changing between DC and AC operation due to the combination
of an electrochromic (EC) and electrochemiluminescent (ECL) layer
in a single device. The EC polymer poly(3,4-ethylenedioxythiophene):poly(styrene
sulfonate) (PEDOT:PSS) serves as the reflective layer, while an ECL
gel made of dimethylsulfoxide (DMSO), poly(lactic-co-glycolic acid) (PLGA), 1-butyl-3-methylimidazoliumbis(oxalato)borate
(BMIMBOB), and tris(bipyridine)ruthenium(II) chloride (Ru2+(bpy)3Cl2) enables the emissive mode. The final
dual-mode devices exhibited their maximum optical power output of
52 mcd/m2 at 4 V and 40 Hz and achieved an EC contrast
of 45% and a coloration efficiency of 244 cm2/C at a wavelength
of 690 nm. The fabricated devices showed clear readability in dark
and light conditions when operated in reflective or emissive modes.
This work demonstrates the applicability of ecofriendly and potentially
biodegradable materials to reduce the amount of hazardous components
in versatile display technologies.