“…C 35 H 31 N 2 OP: M r = 526.59, orange plate, 0.15 × 0.15 × 0.05 mm 3 , monoclinic, space group Cc, a = 21.7254(4), b = 9.3204(4), c = 17.2585(7) Å, α = 90, β = 128.8516(15), γ = 90°, V = 2759.39(18) Å 3 , T = 100(2) K, Z = 4, λ = 0.71073 Å, μ(Mo-Κ α ) = 0.13 mm À 1 , θ range for data collection = 3.0-27.5°, 5108 independent reflections measured, R int = 0.051, d calc = 1.268 g cm À 3 , R1 = 0.050 (for 4274 data with I > 2σ(I)), wR2 = 0.130 (for all data), and 357 refined parameters, largest difference map features between 0.42and À 0.35 e/Å 3 . Crystal data for 2 a • Et 2 O: C 45 H 46 Cl 2 IrN 2 OP • C 4 H 10 O: M r = 999.02, yellow needle, 0.20 × 0.06 × 0.05 mm 3 , monoclinic, space group P2 1 /c, a = 8.5317(17), b = 31.083(6), c = 16.757(3) Å, β = 94.04(3)°, V = 4432.8(15) Å 3 , T = 100(2) K, Z = 4, λ = 0.71073 Å, μ(Mo-Κ α ) = 3.21 mm À 1 , θ range for data collection = 3.1-22.5°, 4811 independent reflections measured, R int = 0.149, d calc = 1.497 g cm À 3 , R1 = 0.067 (for 3161 data with I > 2σ(I)), wR2 = 0.134 (for all data), and 515 refined parameters, largest difference map features between 1.33 and À 1.20 e/Å 3 .…”