Abstract:I would like to thank Jim Barrick for all the support, insight, and guidance he has provided throughout my time at Texas Tech, as well as my committee members, Dustin Sweet and George Asquith, for always being there to help answer any and all questions posed. The time and effort that Jim Barrick, Dustin Sweet, and George Asquith have contributed to furthering my knowledge and assisting with this project is greatly appreciated.Special thanks are given to Greg Wahlman, who initiated this study and provided core … Show more
“…The Wolfcamp shale formation is located in the Permian basin, a sedimentary basin in western Texas and southeastern New Mexico. Application of horizontal drilling and improved hydraulic fracturing technology has transformed this formation from a nonviable shale play into the largest continuous oil and gas production region in the US, , with potential recoverable resources of 20 billion barrels of oil, 16 trillion cubic feet of natural gas, and 1.6 billion barrels of natural gas liquids according to a US Geological Survey assessment . Using conventional primary recovery technology, hydrocarbon recovery rates are generally less than 10% for oil and approximately 20% for gas .…”
Understanding
and improving hydrocarbon yields during
enhanced
oil recovery (EOR) in unconventional reservoirs is complicated by
the intrinsic mineralogical and geochemical heterogeneity of shale
formations. In this study, we utilized small-angle neutron scattering
(SANS) and ultra-small-angle neutron scattering (USANS) to investigate
the degree of oil retention and its location in the nanoporous shale
matrix for two mineralogically distinct shale samples. The two samples,
dubbed “dark” and “light” based on their
color, were taken from adjacent strata in a Wolfcamp shale core. While
both samples contained kerogen, the dark sample contained more kerogen
and clay (43.7 wt %) while the light sample contained more calcite
(54.9 wt %). Samples were presaturated with decane, a model hydrocarbon,
prior to pressure cycling with methane. Results showed significantly
more retention of decane in 1.5–10 nm radius pores of both,
likely indicating that oil is retained within kerogen nanopores. Although
the dark sample had a higher porosity of 8.7%, versus 3.3% for the
light sample, more pores were accessible to decane and a higher percentage
of the imbibed decane was removable from the light sample compared
to the dark sample. The majority of decane was not recoverable for
the dark sample, indicating that EOR with methane can be challenging.
These new findings can help to model expected recoveries of in-place
oil from heterogeneous shale formations, as well as inform improved
EOR strategies.
“…The Wolfcamp shale formation is located in the Permian basin, a sedimentary basin in western Texas and southeastern New Mexico. Application of horizontal drilling and improved hydraulic fracturing technology has transformed this formation from a nonviable shale play into the largest continuous oil and gas production region in the US, , with potential recoverable resources of 20 billion barrels of oil, 16 trillion cubic feet of natural gas, and 1.6 billion barrels of natural gas liquids according to a US Geological Survey assessment . Using conventional primary recovery technology, hydrocarbon recovery rates are generally less than 10% for oil and approximately 20% for gas .…”
Understanding
and improving hydrocarbon yields during
enhanced
oil recovery (EOR) in unconventional reservoirs is complicated by
the intrinsic mineralogical and geochemical heterogeneity of shale
formations. In this study, we utilized small-angle neutron scattering
(SANS) and ultra-small-angle neutron scattering (USANS) to investigate
the degree of oil retention and its location in the nanoporous shale
matrix for two mineralogically distinct shale samples. The two samples,
dubbed “dark” and “light” based on their
color, were taken from adjacent strata in a Wolfcamp shale core. While
both samples contained kerogen, the dark sample contained more kerogen
and clay (43.7 wt %) while the light sample contained more calcite
(54.9 wt %). Samples were presaturated with decane, a model hydrocarbon,
prior to pressure cycling with methane. Results showed significantly
more retention of decane in 1.5–10 nm radius pores of both,
likely indicating that oil is retained within kerogen nanopores. Although
the dark sample had a higher porosity of 8.7%, versus 3.3% for the
light sample, more pores were accessible to decane and a higher percentage
of the imbibed decane was removable from the light sample compared
to the dark sample. The majority of decane was not recoverable for
the dark sample, indicating that EOR with methane can be challenging.
These new findings can help to model expected recoveries of in-place
oil from heterogeneous shale formations, as well as inform improved
EOR strategies.
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