“…For example, it is observed in the positive column of glow discharge [27] and in a transverse discharge [28] in the nitrogen and air, in REP DD in nitrogen [29]. Secondly, the Π state of nitrogen molecule -the upper state of the transitions of (2 + ) nitrogen system is effectively populated at high (150-200 V/(cm·Torr)) values of the reduced electric field strength [30], which are realized in the region of the ionization wave front during the breakdown of the discharge gap [31]. Third, the effective lifetime of the Π state of nitrogen molecule , which is determined by radiative and collisional quenching (1), is less than 1 ns at pressures higher than atmospheric [29]: In (1) , , -pressure, temperature and Boltzmann constant, relatively; , , the reaction rate constants of collisional quenching of Π state (2):…”