“…[2][3][4][5][6][7] LIBS can provide distinct spectral signatures characteristic of all chemical elements in various conditions, such as solid, liquid, gas, and aerosol in industries, environment, medical, biological, aerospace, ocean, etc. [8][9][10][11][12] The measurement of the liquid sample and underwater sample is still a critical challenge, even if several LIBS systems have been developed for undersea trials, such as the laser sensor elements for underwater robotics, compact deep-sea LIBS prototype, 13,14 LIBS liquids analyzer developed by Applied Photonics Ltd. The plasma lifetime is very short for 1 underwater measurement due to the pressure, fluctuation, and quenching effects of liquid.…”