Laser-induced deposition of copper from deep eutectic solvents: optimization of chemical and physical parameters

Shishov, Andrey; Gordeychuk, Dmitry; Logunov, Lev; Levshakova, Aleksandra S.; Andrusenko, Elena V.; Chernyshov, Ivan Yu.; Danilova, E. Ya.; Panov, Maxim S.; Khairullina, Evgeniia M.; Tumkin, Ilya I.

doi:10.1039/d1nj04158d

Cited by 11 publications

(13 citation statements)

References 33 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In order to determine the optimum DES compositions for the synthesis of micropatterns, we prepared DES solutions with different metal salt contents. As it has been shown previously (Shishov et al 2021;Shishov et al 2019), if the concentration of metal salt in the solution is low, the resulting deposits have discontinuous structures and have poor adhesion. On the other hand, if the concentration of metal salt is too high, DESs solutions have a tendency to delaminate.…”

Section: Resultsmentioning

confidence: 69%

See 1 more Smart Citation

Modification of nickel micropatterns for sensor-active applications from deep eutectic solvents

et al. 2023

Self Cite

View full text Add to dashboard Cite

In this work, we proposed a rapid single-stage laser-induced fabrication of bimetallic micro-patterns on an oxide glass surface using deep eutectic solvents (DESs) consisting of choline chloride, citric acid along with nickel, copper and cobalt acetates as metallization solutions. The resulting bimetallic micropatterns were tested as working electrodes for non-enzymatic determination of dopamine. The linear range for dopamine detection was found to be 1-500 µM, with a sensitivity of 340.4 µA mM −1 and 615.2 µA mM −1 and a detection limit of 0.36 µM and 0.51 µM for Ni-Cu and Ni-Co sensor, respectively. For the rst time, bimetallic Ni-Cu and Ni-Co structures have been obtained from DESs for high-performance dopamine detection with great potential for further application in non-enzymatic sensing and biosensing.

show abstract

Section: Resultsmentioning

confidence: 69%

“…1). (Shishov et al 2021). A 532 nm diode-pumped continuous laser was used to carry out the laser deposition.…”

Section: Procedures Of Laser-induced Depositionmentioning

confidence: 99%

Modification of nickel micropatterns for sensor-active applications from deep eutectic solvents

et al. 2023

Self Cite

View full text Add to dashboard Cite

show abstract

“…However, the titanium signals indicate the presence of Ti species on the substrate’s surface after the pre-structuring procedure ( Figure S3 ). Furthermore, one may notice the unevenly distributed chloride, which can be assigned to copper chloride (I) (according to previous research [ 39 ]). Their appearance was most likely caused by unsatisfactory cleaning of the samples from the reaction media.…”

Section: Resultsmentioning

confidence: 88%

“…DESs are inexpensive, eco-friendly solutions, which have the ability to dissolve metal salts in high concentrations and at significantly higher boiling points than water and common organic solvents [ 33 , 34 , 35 ]. The combination of these exceptional properties is heavily exploited for the synthesis of various functional materials [ 36 , 37 , 38 ], including the laser-assisted fabrication of copper and nickel electric contacts onto glass substrates [ 39 , 40 ]. Regarding chemical deposition with CW lasers, DESs based on choline chloride and organic acid have dramatically accelerated scanning rates (more than two orders of magnitude), compared to the regular aqueous solution (from ~2.5 µm/s for water-based systems to ~2 mm/s for DES) [ 41 ].…”

Section: Introductionmentioning

confidence: 99%

Direct Laser Writing of Copper Micropatterns from Deep Eutectic Solvents Using Pulsed near-IR Radiation

et al. 2022

Self Cite

View full text Add to dashboard Cite

In this study, we developed a method for the fabrication of electrically conductive copper patterns of arbitrary topology and films on dielectric substrates, by improved laser-induced synthesis from deep eutectic solvents. A significant increase in the processing efficiency was achieved by acceptor substrate pretreatment, with the laser-induced microplasma technique, using auxiliary glass substrates and optional laser post-processing of the recorded structures; thus, the proposed approach offers a complete manufacturing cycle, utilizing a single, commercially available, pulsed Yb fiber laser system. The potential implications of the presented research are amplified by the observation of laser-induced periodic surface structures (LIPSSs) that may be useful for the further tuning of tracks’ functional properties.

show abstract

“…In our previous works, we optimized physical and chemical factors affecting the process of the formation of copper and nickel micropatterns [34]. It was shown that micropatterns with a high copper content can be fabricated using systems based on choline chloride, copper chloride and organic acids (citric or tartaric) [33].…”

Section: Introductionmentioning

confidence: 99%

Rapid and effective method of laser metallization of dielectric materials using deep eutectic solvents with copper acetate

Khairullina

Shishov

Gordeychuk

et al. 2023

Preprint

View full text Add to dashboard Cite

In this paper, we proposed rapid laser-induced synthesis of copper micropatterns on the surface of oxide glass from deep eutectic solvents (DESs) consisting of choline chloride, citric or tartaric acid and copper acetate as copper plating solutions. It was shown that upon irradiation with continuous-wave 532-nm laser radiation, it is possible to increase the deposition rate of copper and create micropatterns with a resistance close to the value of pure metal together with high adhesion to the substrate surface. This metallization method is favorable for the practical use of copper patterns, including in production of new printable microelectronic devices. Thus, we demonstrated the possibility of copper deposition on arbitrary three-dimensional surfaces. Moreover, the resulting copper micropatterns were tested as working electrodes for non-enzymatic glucose. Finally, the proposed technology can be successfully used for design and development of sensor platforms for the electrochemical analysis and microelectronic devices

show abstract

Laser-induced deposition of copper from deep eutectic solvents: optimization of chemical and physical parameters

Abstract: Fabrication of conductive copper structures on the surface of various dielectric materials is quite important in many fields of science.

Cited by 11 publications

References 33 publications

Modification of nickel micropatterns for sensor-active applications from deep eutectic solvents

Modification of nickel micropatterns for sensor-active applications from deep eutectic solvents

Direct Laser Writing of Copper Micropatterns from Deep Eutectic Solvents Using Pulsed near-IR Radiation

Rapid and effective method of laser metallization of dielectric materials using deep eutectic solvents with copper acetate

Contact Info

Product

Resources

About