ENVIRONMENTAL FORENSICS FOR THE CHARACTERIZATION OF UNEXPLODED ORDNANCE IN SOILS AT THE DOLLY SODS WILDERNESS AREA by Amy Richmond Aylor The West Virginia Maneuver Area includes locations within the Dolly Sods Wilderness Area, the Canaan Valley National Wildlife Recreation Area, and private land holdings in Grant, Randolph, and Tucker counties of West Virginia. Between 1943 and 1944, the military trained troops in a 50,000 acre area which is now the Dolly Sods Wilderness area. This training was conducted by the U.S. Department of the Army and involved artillery and mortar training for troops destined for World War II combat in the mountains of Italy. This project focused on characterization and investigation of the environmental contamination resulting from military ordnance existing within areas of the West Virginia Maneuver Area, including the Dolly Sods Wilderness Area-North, Canaan Valley National Wildlife Refuge, and private land holdings in Canaan Valley, West Virginia. Field sampling campaigns were performed in July and August 2007. Field sampling procedures followed USEPA Method 8330b multi-increment sampling. Concentrations of explosive residues and their degradation products are reported for soils retrieved from these areas and analyzed using high performance liquid chromatography (HPLC) coupled with UV-vis detection. The combination of RDX/HMX was found to be present in soils on the surface and to a depth of at least 20.3 cm (8 in.) in this research. iii ACKNOWLEDGEMENTS I would like to thank Dr. Suzanne Bell for supporting the many pursuits that have comprised my journey as a graduate student. Her enthusiasm for education (and life) certainly kept the days interesting. Without her patience and efforts, my graduate education would not be what it is. I sincerely appreciate the guidance Dr. John Quaranta has offered throughout this project. His level of organization held the work together on many occasions and his gentle wisdom and demeanor have provided me with much inspiration. Without his dedication and participation, I would not have had the opportunity to be a part of such a worthy endeavor. I would also like to thank the third member of my thesis committee, Dr. Keith Morris, for his advice, his constructive criticism, and (of course) his song. Without the pleasure of his company and service, my time at West Virginia University would not have been quite the experience it has been. I would like to thank my husband, Will, our canine charges, Vedder and Fredo, and our son, Maddock, for providing the motivation to see this pursuit through, the support at the end of each day during the process, and the purpose for attempting each new endeavor to come. I would also like to thank my parents, Paul and Julie Richmond, my siblings, Mike Richmond and Tracy Gomer, and my nephew, Christopher Gomer for their constant presence, unconditional love, and never-wielding patience. I am overwhelmed with the good fortune to be part of such a special and invaluable family. I could never have accomplished this research wit...