We have analyzed sample surfaces and particles generated during laser processing of tetragonal zirconia, considering ablation in the gas phase and in liquids using different energies and pulse durations. Remarkably, a liquid layer does not only allow collecting nanoparticulate matter and improving the quality of micromachining, but can also enhance material ablation rates.Keywords: ceramic, zirconia, femtosecond laser ablation, micromachining, nanoparticles
IntroductionLaser ablation of tetragonal zirconia, a very hard ceramic widely-used in medical technology [1,2], is the key to highly interesting new applications. On the one hand, short-pulsed laser structuring is the only wear-free method to shape fully sintered substrates, for instance to produce dental crowns [3]. On the other hand, particles that are laser-ablated from the surface of zirconia substrates can be embedded into other products to increase their surface strength. This laser-based nanotechnology approach provides the best results if ablated particles have specific characteristics (such as small size and good dispersion) and if a long-term fixation between such particles and the product is achieved [4]. The investigations show how zirconia ablation by femtosecond laser pulses affects micromachining quality and efficiency on the one hand and the amount and characteristics of generated nanoparticles on the other hand, and how ablation through liquid films can combine both aims.