We have investigated the exchange anisotropy in L1 2 -ordered Mn 3 Ir/Co 65 Fe 35 bilayers with inserting ultra-thin Co Fe 100 ( 65) layer at the interface between L1 2 -Mn 3 Ir and Co 65 Fe 35 layer. The unidirectional anisotropy constant, , was enhanced from 0.93 erg/cm 2 to 1.2erg/cm 2 at the range from 85 to 98 at.% of Co composition in Co Fe 100 insertion layer. The crystal structure of the ultra-thin Co 90 Fe 10 insertion layer was transformed to bcc structure following the bcc structured Co 65 Fe 35 layer during thermal annealing. These results suggest that the enhancement of exchange anisotropy with ultra-thin Co Fe 100 ( 80) insertion layer is attributed to the Co-rich bcc phase formation in the insertion layer.Index Terms-Co Fe 100 ( 80) insertion layer, exchange anisotropy, L1 2 -ordered Mn 3 Ir, unidirectional anisotropy constant, K .