Lanthanide coordination polymers with pyridyl-N-oxide or carboxylate functionalised host ligands

Abstract

ARTICLE

Rapid Access to Triarylated Cyclotriveratrylenes from Threefold Couplings of CTV‐I3 with Triarylbismuth Reagents

“…The pyramidal shape of cyclotriveratrylene with its convergent binding mode is capable of forming coordination complexes . Further CTV‐based systems, such as metallo‐supramolecular assemblies, lanthanide‐based polymeric and discrete complexes, metal‐organic frameworks with permanent porosity, and metallo‐cryptophanes unequivocally suggest the wide applicability of the functionalized CTV core.…”

Sorption Properties and Nitroaromatic Explosives Sensing Based on Two Isostructural Metal–Organic Frameworks

“…1f) belongs to a (6,3)-connected kgd topology with the Schläfli symbol of (4 3 ) 2 (4 6 •6 6 •8 3 ). [41][42][43] The double-layers are packed together with ABC fashion by aromatic π-π stacking (3.827 Å) to form a 3D supermolecular architecture ( Fig. 1c-e).…”

Coordination polymers with embedded recognition sites: lessons from cyclotriveratrylene-type ligands

“…Pillararenes, crown ethers, cucurbiturils and cyclodextrins have also been employed. Our own work, [9][10][11][12][13][14][15][16][17][18][19][20][21] alongside that of other research groups, [22][23][24][25][26] has investigated the use of functionalised cyclotriveratrylenes (CTVs) as bridging ligands for coordination polymers. Cyclotriveratrylene (CTV) is a bowl-shaped molecular host with a tribenzo [a,d,g] cyclononatriene core.…”