In order to analyze the coupled influence of temperature and humidity on early-age concrete (including cement and copper tailings), a mathematical model is introduced on the basis of the Krstulovic-Dabic hydration reaction kinetic equations. In such a framework, the influence of hydration-released heat and water consumption are also taken into account. The results provided by such a model are verified by means of experiments and related sensor measurements. The research results show that this model can adequately predict the internal temperature and the humidity temporal evolution laws.
KEYWORDSComposite cementitious materials; cement hydration; micro-structure; diffusion coefficient; coupled of heat and moisture Nomenclature A: empirical coefficient, m/h a: constant related to temperature B: empirical coefficient, m/h b: constant related to humidity C: specific heat capacity of concrete, J/(kg•°C) D: hydration degree, % D c : hydration degree of cement, % D 28 : hydration degree when cement is hydrated for 28 days, % E: activation energy of hydration, J/mol E s : diffusion activation energy, J/mol F w : humidity flux H: hydration relative humidity, % H s : relative humidity induced by self-drying of concrete, % H s-max : maximum relative humidity induced by self-drying of concrete, % H E : relative humidity of surrounding environment, % h: constant related to porosity K NG : rate constant of NG process K I : rate constant of I process K D : rate constant of D process This work is licensed under a Creative Commons Attribution 4.0 International License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.