1962
DOI: 10.1021/ba-1962-0034.ch001
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Kinetics of Emulsion Polymerization

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Cited by 69 publications
(19 citation statements)
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“…The data set of Ryabova et al [122] seems to show a plateau for X < 10% but this might also be a broad initial peak as expected after particle nucleation and clearly expressed by the data of van der Hoff [146] where f 1 increases initially and peaks at about a conversion of 10%. From all the data only the set of Stähler [123] also contains average particle sizes showing expectedly decreasing f 1 with increasing d p .…”
Section: Microscopic Modelingmentioning
confidence: 79%
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“…The data set of Ryabova et al [122] seems to show a plateau for X < 10% but this might also be a broad initial peak as expected after particle nucleation and clearly expressed by the data of van der Hoff [146] where f 1 increases initially and peaks at about a conversion of 10%. From all the data only the set of Stähler [123] also contains average particle sizes showing expectedly decreasing f 1 with increasing d p .…”
Section: Microscopic Modelingmentioning
confidence: 79%
“…Figure 14. A) Literature data of experimental values for styrene/polystyrene showing the change of the monomer volume fraction per latex particle (f 1 ) during emulsion polymerization of styrene in dependence on the monomer conversion (X); triangles, [146] squares, [122] and circles. [123] B) f 1 in dependence on average particle size (d p,u unswollen average diameter from turbidity measurements), experimental values from ref.…”
Section: Microscopic Modelingmentioning
confidence: 99%
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“…5,6,7 However, the kinetic behavior of emulsion polymerization using oil-soluble initiators has been reported to be similar to the kinetics obtained with water-soluble initiators. 2,7,8 Thus, the conclusion is there must be some mechanism for the formation of single radicals inside the polymer particles when oil-soluble initiators are used. The various mechanisms proposed can be divided into two categories:…”
Section: Introductionmentioning
confidence: 87%
“…Single radicals formed by desorption from the particle of one of the two radicals formed by initiator decomposition. 5,6,7 2. Radicals formed in the aqueous phase from the fraction of oil-soluble initiator dissolved in the water.…”
Section: Introductionmentioning
confidence: 99%