“…However, proper control of the microstructure, grain size, porosity, and crystallinity have remained major issues [28,29,40,[45][46][47][48]. Physical deposition techniques such as pulsed laser deposition (PLD) are also challenging for the growth of PZT thin films due to the high volatility of Pb in PZT that leads to its non-stoichiometric ablation and results in Pb-deficient PZT films exhibiting poor FE properties [49,50,51]. Among the few reports on the PLD grown PLZT thin films almost all of them discuss polycrystalline PLZT thin film properties [41,[52][53][54].…”