Isothermal vapor–liquid equilibrium measurements
of three
binary systems, H2S + propane, H2S + n-butane, and H2S + n-pentane,
have been performed with a static synthetic apparatus at low temperatures.
The method of Barker has been implemented to determine the corresponding
nonrandom two-liquid (NRTL) parameters and to calculate the liquid
mole fractions. The results have been further used along with literature
data to adjust binary interaction parameters of the Peng–Robinson
equation of state. Good agreement with Dechema values has been found.