“…Se and13 C NMR data (, ppm) for selected metal selenothiocarbamates a The homoleptic bis-and tris-(selenothiocarbamate) complexes M[Se(S)CNR2]x (for x = 3, M = Ga, In, Tl, Cr, Fe, Co (6), Rh and Mn; for x = 2, M = Zn, Cd, Pb, Ni, Pd and Cu(9) and for x =1, M = Tl and Ag), for which compounds 6[33] and 9[40] have been structurally characterised, were prepared by reaction of the ammonium, sodium or potassium selenothiocarbamate salts with either the metal trichloride or the metal sulphate[12,41,42].…”