Iron-based metal–organic framework, Fe(BTC): an effective dual-functional catalyst for oxidative cyclization of bisnaphthols and tandem synthesis of quinazolin-4(3H)-ones

Abstract

Fe(BTC) catalyzed synthesis of spirodienones and quinazolin-4(3H)-ones.

A Multifunctional Zirconium‐Based Metal–Organic Framework for the One‐Pot Tandem Photooxidative Passerini Three‐Component Reaction of Alcohols

“…Herein, in regard of the intriguing properties of the Zr‐based MOFs and in continuation of our current research interests on porous materials as catalysts in multicomponent and tandem oxidation reactions,, we were encouraged to design and synthesize a stable multifunctional Zr–MOF (Zr–MOF–FePC, PC=2‐pyridinecarboxaldehyde) bearing both active Lewis acid and photocatalyst sites, which can perform the tandem photooxidative P‐3C reaction in one‐pot (Scheme ). The tandem methodology not only further explores MOFs in heterogeneous catalysis and photocatalysis, but also outlines a facile and efficient approach for the direct synthesis of α‐acyloxy amides from alcohols.…”

Engineering Metal–Organic Framework Catalysts for C−C and C−X Coupling Reactions: Advances in Reticular Approaches from 2014–2018

“…The reaction was also extended to synthesize quinazolin-4(3H)-ones from aryl alcohols through a tandem CÀNc oupling reaction. [111]). The as-obtained MOF was characterized by using Scheme27.…”

“…acid. Fe(BTC) driven CÀNc oupling of benzyl alcohol with o-aminobenzamide [111]. The MOF had asurfacearea of 680 m 2 g À1 .XPS confirmed the presence of both Fe II and Fe III ions in the MOF.…”

Aerobic Copper Catalytic Oxidation of Methylene and Arylidenebisnaphthols: A Green and Efficient Synthesis of Spironaphthalenones

“…Depending on the conditions, the reaction proved to be stereoselective,,, or lead to a mixture of diastereoisomers ,,. Moreover, the reaction conditions are very often stoichiometric and only more recently catalytic conditions were reported.…”