The Co−Mo system is characterized by a small negative heat of formation being −7 kJ/mol, which provides a small driving force for alloying. In the case of the initial multilayered films with closest-packed semi-coherent interfaces, solid-state interfacial reaction is frustrated upon thermal annealing even at a temperature up to 600 • C. However, amorphization through interfacial reaction was achieved upon ion irradiation as the intensive ion irradiation can elevate the initial energetic state by the irradiation energy as well as destroy the semi-coherent interfaces and thus drive atomic mixing in the films eventually becoming disordered.
PACS: 64.70.Kb; 61.82.Bg; 68.65.+g Amorphous alloys have various inviting properties and have attracted much research effort since the 1950s [1], when the first amorphous films were synthesized by quenching a vapor mixture of two constituent metals onto a cryogenically cooled substrate. However, the films so obtained were very unstable and they even recrystallized at room temperature. In the following years a variety of techniques have been developed to form amorphous phase. In the early 1960s, the liquid melt quenching method was reported by Duwez et al. to fabricate Au−Si amorphous alloys [2]. In the 1980s, two other effective glass-producing techniques were proposed. One is ion mixing of multilayered films, which features a high effective cooling speed of 10 13 -10 14 K/s and has produced a great number of amorphous alloy phases including those recognized previously as non-glass-forming ones upon liquid melt quenching [3]. The other is solid-state reaction, which was first introduced by Schwarz and Johnson who reported the formation of amorphous alloy films just by thermal annealing the polycrystalline Au−La multilayers [4]. From then on, many studies have been carried out on the amorphization induced by ion-beam mixing and thermal annealing in the binary metallic multilayered films [5,6].One common characteristic of ion-mixing (IM) and solidstate reaction (SSR) methods is that they both start with multilayered films. It is obvious that the multilayered films consist of a certain number of interfaces, and the detailed structure of the interfaces, for example, texture and smoothness, should play some roles in influencing the amorphization behavior. Previous studies show that in the binary metal system with a large negative heat of formation, the interfacial structures have various influences on the solid-state reaction, i.e. the disordered interfaces can act as the nucleation sites for the amorphous phase [7], and the semi-coherent interfaces work as a nucleation and kinetic barrier to amorphization [8].In this study, the Co−Mo system with a small negative heat of formation (−7 kJ/mol) was selected for a comparative study to investigate the effect of semi-coherent interfaces on the alloying behavior when Co−Mo multilayered films are subjected to ion irradiation and thermal annealing.