Investigation on the crystal growth, molecular structure and nonlinear optical susceptibilities of 2-[2-(4-Ethoxy-phenyl)-vinyl]-1-ethyl-stilbazolium iodide (EESI) by Z-scan technique using He–Ne laser for third-order nonlinear optical applications

Senthil, K.; Kalainathan, S.; Kondo, Yoshihiko; Hamada, Fumio; Yamada, Manabu

doi:10.1016/j.optlastec.2016.10.019

Cited by 35 publications

(4 citation statements)

References 63 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The overall characterization results implied that the synthesized DMSB material showed superior NLO response and 50 2.04 × 10 −14 VMST 51 9.696 × 10 −12 4MBS 52, 53 11.04 × 10 −8 DSMOS 13 5.05 × 10 −8 it can be utilized for all-optical switching and optical limiting applications.…”

Section: Roughness Parameters Valuesmentioning

confidence: 98%

A novel stilbazolium derivative crystals of 4-[2-(4-dimethyl amino-phenyl)-vinyl]-1-methyl-pyridinium⁺ bromide⁻ (DMSB) single crystal: exploration of the growth, molecular structure, linear optical, and third order nonlinear properties

Vinayagamoorthy,

Rani,

Kalainathan

et al. 2023

RSC Adv.

View full text Add to dashboard Cite

show abstract

Section: Roughness Parameters Valuesmentioning

confidence: 98%

A novel stilbazolium derivative crystals of 4-[2-(4-dimethyl amino-phenyl)-vinyl]-1-methyl-pyridinium⁺ bromide⁻ (DMSB) single crystal: exploration of the growth, molecular structure, linear optical, and third order nonlinear properties

Vinayagamoorthy,

Rani,

Kalainathan

et al. 2023

RSC Adv.

View full text Add to dashboard Cite

show abstract

“…The iso-surfaces of the 3D molecular electrostatic potential (MEP) plot provide charge distribution of molecules and also it contributes to the interaction between the molecular structure with its physicochemical characteristics like partial charges, dipole moment, chemical reactivity, and electronegativity [78,79]. Due to this desire, the MEP map of B4ATCZ is generated at the B3LYP/6-311?…”

Section: Molecular Electrostatic Potential Surfacementioning

confidence: 99%

Investigation on the optical, spectral, electrical, mechanical, and laser damage threshold studies of bis (4-acetylanilinium) tetrachloridozincate (B4ATCZ) crystal

Suriya

Manimaran

Boaz

et al. 2021

J Mater Sci: Mater Electron

View full text Add to dashboard Cite

An efficient semi-organic nonlinear optical bis (4-acetylanilinium) tetrachloridozincate [(C8H10NO)2 ZnCl4] (B4ATCZ) single crystal was synthesized and successfully grown by the slow evaporation method. The single-crystal X-ray diffraction data confirm that B4ATCZ crystallized into an orthorhombic crystal system (Cmca). The UV–Vis–NIR transmittance spectrum was taken to assess the optical transmission, cut-off wavelength, and bandgap energy. The TG–DSC investigation ensures that the B4ATCZ is stable up to 235 °C. The mechanical behavior of the B4ATCZ compound was determined by Vickers Microhardness analysis. The surface laser-induced damage threshold value of the grown B4ATCZ crystal was endowed to be 19.78 GW/cm2 on testing with 1064 nm Nd: YAG laser radiation. The positive photoconductive properties and charge transport mechanism of B4ATCZ crystal were analyzed through photoconductivity and dielectric studies. The electron excitation and lifetime measurements of the molecules in the B4ATCZ crystal were studied by fluorescence spectral analysis. The HOMO–LUMO analysis evidently interprets the occurrence of N–H⋯O and N–H⋯Cl intermolecular hydrogen bonds influencing the charge transfer in the system. The electrostatic potential surface reveals the possible sites for hydrogen bonding electrophilic and nucleophilic interactions. Third-order nonlinear optical activity evaluated by the Z-scan measurements indicates the self-focusing and reverse saturable absorption in the crystal. The aforesaid results affirm that the metal-organic B4ATCZ is a potential material for optoelectronic and nonlinear optical device applications.

show abstract

“…In the field of optical switching and optoelectronic device fabrications there is a huge need for thermally stable materials, which can with stand at high temperature when they are exposed to laser continuously [29].Thermogravemetric(TG) and Differential scanning (DSC) studies were carried concomitantly on LHKB 5 powder sample 4.739 mg. Fig.…”

Section: Thermal Analysismentioning

confidence: 99%

Investigation on new NLO material L-histidine potassium pentaborate (LHKB5)

Karnan¹,

Prabhakaran²

2019

IJSRPAS

View full text Add to dashboard Cite

A new nonlinear optical crystal L-histidine potassium pentaborate single crystal was grown from aqueous solution by the slow evaporation solution growth technique to analyse its suitability for NLO device applications. It belongs to the orthorhombic crystal system which is confirmed by single crystal X-ray diffraction analysis. The UV-visible analysis was carried out on LHKB 5 crystal to find out cut-off wavelength and the energy gap of the material was found to be 245 nm and 5.05 eV. The presence of L-histidine potassium pentaborate on grown material was confirmed by FTIR analysis. TG-DSC analysis determines that the material has two stages of decomposition and it has three stages of weight loss. From DTA curve a sharp endothermic peak at 192.45°C shows good crystallinity and corresponds to the melting of the grown crystal. The mechanical strength of the material is calculated using Vicker's microhardness. Grown crystal shows that the material is very much suitable for a second harmonic generation and frequency conversion applications.

show abstract

Investigation on the crystal growth, molecular structure and nonlinear optical susceptibilities of 2-[2-(4-Ethoxy-phenyl)-vinyl]-1-ethyl-stilbazolium iodide (EESI) by Z-scan technique using He–Ne laser for third-order nonlinear optical applications

Cited by 35 publications

References 63 publications

A novel stilbazolium derivative crystals of 4-[2-(4-dimethyl amino-phenyl)-vinyl]-1-methyl-pyridinium⁺ bromide⁻ (DMSB) single crystal: exploration of the growth, molecular structure, linear optical, and third order nonlinear properties

A novel stilbazolium derivative crystals of 4-[2-(4-dimethyl amino-phenyl)-vinyl]-1-methyl-pyridinium⁺ bromide⁻ (DMSB) single crystal: exploration of the growth, molecular structure, linear optical, and third order nonlinear properties

Investigation on the optical, spectral, electrical, mechanical, and laser damage threshold studies of bis (4-acetylanilinium) tetrachloridozincate (B4ATCZ) crystal

Investigation on new NLO material L-histidine potassium pentaborate (LHKB5)

Contact Info

Product

Resources

About

Investigation on the crystal growth, molecular structure and nonlinear optical susceptibilities of 2-[2-(4-Ethoxy-phenyl)-vinyl]-1-ethyl-stilbazolium iodide (EESI) by Z-scan technique using He–Ne laser for third-order nonlinear optical applications

Cited by 35 publications

References 63 publications

A novel stilbazolium derivative crystals of 4-[2-(4-dimethyl amino-phenyl)-vinyl]-1-methyl-pyridinium+ bromide− (DMSB) single crystal: exploration of the growth, molecular structure, linear optical, and third order nonlinear properties

A novel stilbazolium derivative crystals of 4-[2-(4-dimethyl amino-phenyl)-vinyl]-1-methyl-pyridinium+ bromide− (DMSB) single crystal: exploration of the growth, molecular structure, linear optical, and third order nonlinear properties

Investigation on the optical, spectral, electrical, mechanical, and laser damage threshold studies of bis (4-acetylanilinium) tetrachloridozincate (B4ATCZ) crystal

Investigation on new NLO material L-histidine potassium pentaborate (LHKB5)

Contact Info

Product

Resources

About

A novel stilbazolium derivative crystals of 4-[2-(4-dimethyl amino-phenyl)-vinyl]-1-methyl-pyridinium⁺ bromide⁻ (DMSB) single crystal: exploration of the growth, molecular structure, linear optical, and third order nonlinear properties

A novel stilbazolium derivative crystals of 4-[2-(4-dimethyl amino-phenyl)-vinyl]-1-methyl-pyridinium⁺ bromide⁻ (DMSB) single crystal: exploration of the growth, molecular structure, linear optical, and third order nonlinear properties