We fabricated p + -, p-, and p % -Si/n-4H-SiC junctions by surface activated bonding (SAB). We investigated their electrical properties by measuring their current-voltage (I-V) characteristics at raised ambient temperatures, capacitance-voltage (C-V) characteristics at various frequencies, and capacitance-frequency (C -f ) characteristics at room temperature. The activation energy of their reverse-bias current and the flat-band voltage in their C-V characteristics, which were estimated to be 0.97-1.01 eV and 0.83-0.84 V, respectively, were insensitive to the concentrations of acceptors in Si substrates. The relaxation times estimated from the C-f characteristics were 0.8 and 1.5 µs for the p-Si/n-4H-SiC and p % -Si/n-4H-SiC junctions, respectively. The results are explained by a scheme wherein Fermi level pinning occurs at the Si/4H-SiC interfaces fabricated by SAB.