The effect of frequency detuning away from the line center on the radiative parameters of pulsed CO 2 lasers is studied by numerical modelling. It is shown that the temporal, energy, and spectral characteristics of the output can be controlled by varying the detuning and other parameters. Output pulses with a high peak power have an essentially unremovable, relatively long "tail" owing to the rotational bottleneck effect. The energy of the laser pulse is greatest at the line center. For certain values of the parameters, a maximum peak power is attained in the wings of the line, rather than at its center. The amount of sweeping depends on the sign of the detuning and is typically no more than 10 MHz.Keywords: CO 2 laser, frequency detuning of radiation, frequency sweeping, rotational bottleneck effect.Introduction. Various types of CO 2 lasers are currently in widespread use in scientific research and in different areas of the economy [1-6]. The entire range of their applications can be divided arbitrarily into two areas: nonselective (high power) and selective interactions with matter [3-6]. In the first, the energy parameters (energy and power) of the output radiation are most important. This is typical of the applications CO 2 lasers in cutting, welding, thermal processing, etc. In the second case, i.e., when the task involves a selective interaction of the laser radiation with matter, such parameters of the output as wavelength, spectral width, and stability are of primary importance. Examples of these applications include laser isotope separation, laser ranging of different objects in the atmosphere, laser spectroscopy of vibrationally excited molecules, etc.It is known that the emission spectrum of CO 2 lasers operating on lines of ordinary, sequential, hot, and other transitions, consists of a set of discrete, nonequidistant spectrum lines which correspond to individual vibrational-rotational transitions [1,6]. Nonlinear crystals are used to shift the output of these lasers from one spectral region to another for applications involving selective interactions with matter.TEA CO 2 lasers usually emit pulses consisting of a powerful (≥1 MW), dominant peak of duration ~100 ns, and a "tail" lasting ≥1 μs which usually contains ≥50% of the pulse energy. It is known that the tail of these laser pulses essentially does not undergo conversion to the second harmonic because of its low intensity; the tail also greatly reduces the efficiency of frequency doubling because of the thermal heating it causes. Thus, the use of short high-intensity pulses is of fundamental importance for efficient second harmonic generation and other nonlinear optical transformations [6]. This paper is devoted to a study of the feasibility of controlling the output parameters of CO 2 lasers (primarily to produce short, high-power pulses) for nonlinear frequency conversion applications by varying the frequency detuning (from the line center) and other characteristics. There are essentially no studies of this sort in the literature, except for ...