2013
DOI: 10.1016/j.cej.2013.03.100
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Investigation of gas permeation behavior in facilitated transport membranes: Relationship between gas permeance and partial pressure

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Cited by 51 publications
(31 citation statements)
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“…Figures a and a indicate that increasing the H 2 partial pressure difference decreases the permeance. Similar behavior has been observed in other studies . This might be attributed to more hydrogen ions in the lattice at high pressure difference that makes the movement of the ions relatively difficult, thereby reducing the permeance.…”
Section: Resultssupporting
confidence: 87%
“…Figures a and a indicate that increasing the H 2 partial pressure difference decreases the permeance. Similar behavior has been observed in other studies . This might be attributed to more hydrogen ions in the lattice at high pressure difference that makes the movement of the ions relatively difficult, thereby reducing the permeance.…”
Section: Resultssupporting
confidence: 87%
“…Firstly, according to the formulas reported in the literature [31], the CO 2 flux (the CO 2 permeance multiplied by the pressure difference) increases gradually with increasing feed pressure, and the increased CO 2 molecules will occupy a part of the transport channels of H 2 , which restrains the H 2 transport in the membrane. Therefore, with increasing feed pressure, the H 2 permeance of the PVAm-MEA/PS and PVAm-DEA/PS membranes decreases continuously according to the formulas reported in the literature [31]. Secondly, the membrane compaction may also occur at high pressure, which would decrease the H 2 permeance of the PVAm-MEA/PS and PVAm-DEA/PS membranes.…”
Section: Co 2 Permeance and Co 2 /H 2 Selectivity Of Pvam-sma/ps Compmentioning
confidence: 99%
“…The CO 2 permeability in Fig. 12(a) facilitated equation as reported [27,[57][58][59], and CO 2 diffusion coefficient (D A ) and diffusion coefficient of CO 2 -carrier complex (D AC ) contributing to the total diffusion coefficient are obtained by facilitated equation (4) and calculated equation parameters are listed ( Table 2). …”
Section: 4 Effect Of Feed Pressurementioning
confidence: 99%