Abstract:Anti-ferromagnetic interaction was observed in a new crystal that consists of mononuclear Co II complexes, namely [Co(PMP)(N 3 )] (PMP ¼ 2,9-bis(pyridin-2-methoxyl)-1,10-phenanthroline); in the mononuclear complex Co II has a distorted trigonal-bipyramidal geometry. Analysis for the crystal structure indicates six magnetic coupling pathways among adjacent complexes, in which three involve -stacking and the other three deal with intermolecular interactions. The fitting for the variable-temperature magnetic susc… Show more
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