Abstract:Este trabalho relata um estudo sistemático do comportamento estrutural e elétrico de três fases ternárias do sistema Ta x Mo 1-x S 2 (x = 0,55, 0,75 e 0,90) e de seus compostos de intercalação resultantes das inserções química e eletroquímica de lítio, assim como das intercalações de piridina e poli(óxido de etileno). As três fases foram preparadas pela reação direta de seus elementos constituintes, sem qualquer outro aditivo, a 900 o C em atmosfera inerte. Os compostos resultantes foram caracterizados por mei… Show more
“…33 In the field of transition metal dichalcogenides, to the best of our knowledge, crown ethers have been only utilized as Li ions-containing intercalants within MoS2 exfoliated nanosheets serving as potential electrochemical switches. 34,35 The selective recognition of cations by tuning the size of the oxygencontaining macrocycles offers the advantage of developing responsive electrochemical platforms based on the host-guest interactions, arising from the stabilization of the cations within the macrocyclic polyether tether. Furthermore, it is known that B15C5 efficiently hosts sodium cations with high binding affinity.…”
We describe the basal plane functionalization of chemically exfoliated molybdenum disulfide (ce-MoS2) nanosheets with a benzo-15-crown-5 ether (B15C5), promoted by the chemistry of diazonium salts en route the fabrication and...
“…33 In the field of transition metal dichalcogenides, to the best of our knowledge, crown ethers have been only utilized as Li ions-containing intercalants within MoS2 exfoliated nanosheets serving as potential electrochemical switches. 34,35 The selective recognition of cations by tuning the size of the oxygencontaining macrocycles offers the advantage of developing responsive electrochemical platforms based on the host-guest interactions, arising from the stabilization of the cations within the macrocyclic polyether tether. Furthermore, it is known that B15C5 efficiently hosts sodium cations with high binding affinity.…”
We describe the basal plane functionalization of chemically exfoliated molybdenum disulfide (ce-MoS2) nanosheets with a benzo-15-crown-5 ether (B15C5), promoted by the chemistry of diazonium salts en route the fabrication and...
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