In this paper, we have implemented an efficient and novel technique for multi-label class prediction using associative rule mining. Many of the research works for the classification have been carried out on single-label datasets, but it is not useful for all real-world application accounting to multi-label datasets like scene classification, text categorization, etc. Hence, we propose an algorithm for performing multi-label classification and solve the problems which come across in the domain pertaining to single-label classification. Our novel technique (ARM-MLC) will aim in enhancing the accuracy of any decision-making processes. Here, in multi-label classification, based on our work, we aim to predict the multiple characters of the instances.