Abstract:Abstract. Composition gradients in miscible liquids can create volume forces resulting in various interfacial phenomena. Experimental observations of these phenomena are related to some difficulties because they are transient, sufficiently weak and can be hidden by gravity driven flows. As a consequence, the question about their existence and about adequate mathematical models is not yet completely elucidated. In this work we present some experimental evidences of interfacial phenomena in miscible liquids and … Show more
“…denoting the thermodynamic pressure ( f -the free-energy density for the homogeneous phases). The second term on the right-hand-side in equation ( 1) is the Korteweg stress, as introduced by Korteweg (1901) and subsequently studied by several authors (Bessonov et al 2004, Zoltowski et al 2007, Bessonov et al 2008. The Korteweg stress describes the contribution of the capillary forces and represents in the phase field formalism the substitute of the kinematic boundary condition at the liquid-gas interface (Colinet et al 2001).…”
We describe the self-propulsion of two sessile drops induced by surface tension gradients at the droplet interfaces using a three-dimensional phase field model. We study the problem for the low viscosity regime when the width of the connecting neck between the interacting drops increases linearly with increasing t 1/2 and the merger is dominated by capillary forces. We investigate the dependence of the displacement achieved by self-propulsion on viscous shearing as well as the internal flow structure during the coalescence process.
“…denoting the thermodynamic pressure ( f -the free-energy density for the homogeneous phases). The second term on the right-hand-side in equation ( 1) is the Korteweg stress, as introduced by Korteweg (1901) and subsequently studied by several authors (Bessonov et al 2004, Zoltowski et al 2007, Bessonov et al 2008. The Korteweg stress describes the contribution of the capillary forces and represents in the phase field formalism the substitute of the kinematic boundary condition at the liquid-gas interface (Colinet et al 2001).…”
We describe the self-propulsion of two sessile drops induced by surface tension gradients at the droplet interfaces using a three-dimensional phase field model. We study the problem for the low viscosity regime when the width of the connecting neck between the interacting drops increases linearly with increasing t 1/2 and the merger is dominated by capillary forces. We investigate the dependence of the displacement achieved by self-propulsion on viscous shearing as well as the internal flow structure during the coalescence process.
“…Examples of such phenomenon is the mixing of water and glycerin, and water and ethanol. The study of miscible liquids is motivated by problems in oil recovery, hydrology, polymer blends, groundwater pollution and filtration [1,2,3,6,15].…”
In this paper we prove the existence and uniqueness of a solution to the nonstationary two dimensional system of equations describing miscible liquids with nonsmooth, multivalued and nonmonotone boundary conditions of subdifferential type. We employ the regularized Galerkin method combined with results from the theory of hemivariational inequalities.
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