Inhibitory effect of Senecio anteuphorbium as green corrosion inhibitor for S300 steel

Idouhli, Rachid; Koumya, Yassine; Khadiri, M.; Aityoub, A.; Abouelfida, A.; Benyaich, A.

doi:10.1007/s40090-019-0179-2

Cited by 68 publications

(27 citation statements)

References 50 publications

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“…The juice of S anteuphorbium is commonly used by populations of some areas in order to treat rheumatism and burns pain 25 . A recent study has shown its usage as a green corrosion inhibitor for S300 steel 26 . However, the Senecio genus is a source of pyrrolizidine alkaloids; it is the most common poisonous component and can therefore cause hepatotoxicity and carcinogenesis 27 .…”

Section: Introductionmentioning

confidence: 99%

Identification of the chemical composition of six essential oils with mass spectroscopy and evaluation of their antibacterial and antioxidant potential

Irahal

Lahlou

Hmimid

et al. 2021

Flavour & Fragrance J

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This study determined the chemical composition of Cinnamomum verum J.Presl, Cistus ladaniferus L., Laurus nobilis L., Senecio anteuphorbuim, Boswellia serrata Roxb. ex Colebr. and Schinus molle L. essential oils (EOs) by gas chromatography‐mass spectrometry. Moreover, the six EOs were screened in order to reveal their antibacterial and antioxidant activities. They were initially tested against six pathogenic bacteria: Staphylococcus aureus (MRSA: methicillin‐resistant Staphylococcus aureus), Escherichia coli (ESBL: extended‐spectrum β‐lactamases), Enterococcus faecalis (VRE: vancomycin‐resistant enterococcus), Klebsiella pneumoniae (CRK: carbapenem‐resistant klebsiella), clinical isolate Staphylococcus aureus and Escherichia coli ATCC 25922. Then, the antioxidant effect was assessed by β‐carotene‐linoleic acid. Cinnamomum verum J.Presl, Cistus ladaniferus L. and Laurus nobilis L. exhibited the greatest antibacterial activity except Boswellia serrata Roxb. ex Colebr. oil. But this last one showed the highest antioxidant activity (85.75%) comparable to that of BHT (98.25%). The principal component analysis between the antibacterial activity and the twenty major components of six EOs revealed that α‐pinene, β‐pinene, 4‐carene, α‐phellandrene, 1,8‐cineole, linalool, 1,3,8‐p‐menthatriene, α‐terpineol, cinnamyl alcohol and cinnamaldehyde are responsible for their antibacterial activity against multi‐resistant strains. From this study, the results obtained show that the EOs may constitute an alternative to the emergence of multidrug‐resistant bacteria.

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Section: Introductionmentioning

confidence: 99%

Identification of the chemical composition of six essential oils with mass spectroscopy and evaluation of their antibacterial and antioxidant potential

Irahal

Lahlou

Hmimid

et al. 2021

Flavour & Fragrance J

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“…Chemisorption is one that has been listed by many authors. Several studies, for example, Chaudhari and Patel [80], Salinas-Solano et al [81], and Idouhli et al [82], have concluded that chemisorption forms a strong interaction between the metal and inhibitors, as shown in Figure 7. Thus, a film is formed on top of the metal surface.…”

Section: Inhibition Mechanismmentioning

confidence: 98%

“…On the other hand, chemisorption happens when the value of ∆G 0 ads is less than −40 kJ/mol. Idouhli et al [82] explained that chemisorption involves the sharing of molecules of the inhibitors with the metal surfaces. Chemisorption is a stronger type of adsorption compared to physisorption.…”

Section: Inhibition Mechanismmentioning

confidence: 99%

A Review on Plants and Biomass Wastes as Organic Green Corrosion Inhibitors for Mild Steel in Acidic Environment

Reza

Akhmal

Fadil

et al. 2021

Metals

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Acid corrosion is a problem pertaining to corrosion that involves an acid solution. It is important to treat metal to preserve its integrity. Thus, acids are utilized to clean and treat metal surfaces. In return, this may lead to over-etching and metal degradation. Corrosion inhibitors were introduced as a solution for the issue. However, there are some problems associated with the usage of conventional corrosion inhibitors. Traces of nitrites and chromates that are present in the inhibitors may lead to serious health and environmental issues. As a solution, organic green corrosion inhibitors have been studied to replace the conventional corrosion inhibitors. These inhibitor molecules form a protective layer on top of the metal surface to suppress metal dissolution when added to the acid solution. This process prevents direct contact between the metal surfaces and the acid environment. This study explores the usage of natural resources and biomass wastes as the basis for organic green corrosion inhibitors. This study also provides some suggestions for new biomass wastes that can be studied as new organic corrosion inhibitors, and it is aimed at opening the perspective of researchers on exploring new organic inhibitors by using natural resources and biomass wastes.

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“…Moreover, the corrosion potential (Ecorr) is slightly shifted than the blank (≈15-77 mV), as described in Table 9. In general, an inhibitor is classified as an anodic or a cathodic type if the displacement in corrosion potential (Ecorr) values against the blank is larger than 85 mV 45,46 . In the present study, Ecorr shifted within 85 mV, suggesting the mixed type inhibitor.…”

Section: Homo-lumo Analysismentioning

confidence: 99%

Synthesis, Characterization, Theoretical and Electrochemical Studies of Pyrazoline Derivatives

Soumane¹,

Baouid²,

Hadrami³

et al. 2020

Mediterr.J.Chem.,

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The reaction of 1,3-dipolar cycloaddition of trans-anethole and three different diarylnitrilimines bearing different substituents X= {H, CH3, Cl} yield to the creation of three 1,3,4,5-tetrasubstituted pyrazoles. These reactions produce a single regioisomer. These compounds' structures were studied using diverse spectroscopic techniques such as 1H, 13C NMR, and HRMS. Afterwards, X-ray diffraction is performed at 5-(4-methoxyphenyl)-4-methyl-1,3-diphenyl-4,5-dihydro-1H-pyrazole. Also, Density Functional Theory (DFT) is performed to characterize these cycloadducts.Moreover, these synthesized compounds' molecular geometry and electronic structures have been studied using high-level ab initio calculations and DFT using the B3LYP functional. All geometries have been optimized at the B3LYP/6-311+G(d,p) basis set with different kinds of solvents. In the end, the protection against corrosion of copper surface is tested using these pyrazolines. As a result, the experimental analysis proved that the obtained cycloadducts belong to the pyrazoline family. Also, X-ray diffraction determined the stereochemistry of these compounds. DFT-based calculations revealed the existence of three stable conformations of each compound. The theoretical study and the experimental spectroscopic data showed perfect matching. The electrochemical investigation indicates that these pyrazoline compounds exhibit a good inhibition performance, preventing the degradation of copper in NaCl (3%) solution with a high inhibition efficiency of 80%.

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Inhibitory effect of Senecio anteuphorbium as green corrosion inhibitor for S300 steel

Cited by 68 publications

References 50 publications

Identification of the chemical composition of six essential oils with mass spectroscopy and evaluation of their antibacterial and antioxidant potential

Identification of the chemical composition of six essential oils with mass spectroscopy and evaluation of their antibacterial and antioxidant potential

A Review on Plants and Biomass Wastes as Organic Green Corrosion Inhibitors for Mild Steel in Acidic Environment

Synthesis, Characterization, Theoretical and Electrochemical Studies of Pyrazoline Derivatives

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