“…4, curve 3). Reduction of the TO−LO phonon energy splitting corresponds to the stress relaxation in a silicon oxide layer [11]. The increase in the splitting of TO−LO phonons is associated with stoichiometry growth at the silicon−silicon oxide interface as the SiO 2 content in the SiO/SiO 2 mixture increases [12].…”
Section: Macroporous Silicon Structures With Sio 2 Nanocoatingsmentioning
We investigated the contribution of electron-phonon interaction to the broadening parameter Γ of the Wannier-Stark ladder levels in oxidized macroporous silicon structures with different concentration of Si-O-Si states (TO and LO phonons). The obtained value of the Wannier-Stark ladder parameter Γ is much less than the djacent level energy evaluated from giant oscillations of resonance electron scattering on the surface states. We determined the influence of broadening on the oscillation amplitude in IR absorption spectra as interaction of the surface multi-phonon polaritons with scattered electrons. This interaction transforms the resonance electron scattering in samples with low concentration of Si-O-Si states into ordinary scattering on ionized impurities for samples with high concentration of Si-O-Si states. The transformation takes place at the scattering lifetime coinciding with the period of electron oscillations in the surface electric field.
“…4, curve 3). Reduction of the TO−LO phonon energy splitting corresponds to the stress relaxation in a silicon oxide layer [11]. The increase in the splitting of TO−LO phonons is associated with stoichiometry growth at the silicon−silicon oxide interface as the SiO 2 content in the SiO/SiO 2 mixture increases [12].…”
Section: Macroporous Silicon Structures With Sio 2 Nanocoatingsmentioning
We investigated the contribution of electron-phonon interaction to the broadening parameter Γ of the Wannier-Stark ladder levels in oxidized macroporous silicon structures with different concentration of Si-O-Si states (TO and LO phonons). The obtained value of the Wannier-Stark ladder parameter Γ is much less than the djacent level energy evaluated from giant oscillations of resonance electron scattering on the surface states. We determined the influence of broadening on the oscillation amplitude in IR absorption spectra as interaction of the surface multi-phonon polaritons with scattered electrons. This interaction transforms the resonance electron scattering in samples with low concentration of Si-O-Si states into ordinary scattering on ionized impurities for samples with high concentration of Si-O-Si states. The transformation takes place at the scattering lifetime coinciding with the period of electron oscillations in the surface electric field.
“…86,87 A paper by A. G. Milekhin et al 86 provides a detailed study plasma activated interfaces during annealing. Four methods of activation are utilized, ambient O 2 plasma, O 2 RIE, NH 3 plasma, and RCA immersion.…”
Section: Ecs Journal Of Solid State Science and Technology 3 (4) Q42mentioning
confidence: 99%
“…The same group prepared a second paper in 2006. 86 This paper had a particular focus on the structure of the oxide interlayer during the annealing process.…”
Section: Subsequent High Temperature Annealing At 900mentioning
“…77 The peak at $2110 cm À1 corresponds to the stretching vibration of Si-H in dehydrate groups at the silicon surface. 78,79 The absorption peaks located at $2359, 3245 and 3492 cm À1 assigned to the H-O-H bending mode, symmetric and antisymmetric O-H mode of water. 67,80 The absorption peaks at $2809 and 3400 cm À1 are correspond to the typical O-H vibrations due to the adsorbed water molecule on the surface of MoO x QDs.…”
Section: Crystal Structure and Particle Size Analysismentioning
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