1979
DOI: 10.1063/1.326314
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Infrared quenching of photocapacitance in evaporated ZnS : Ag thin films

Abstract: The deep centers in evaporated ZnS : Ag thin films have been characterized by observation of the infrared quenching of photocapacitance using Schottky barriers. The photoionization energy of holes for transitions from Ag centers to the valence band edge is determined to be 0.56 eV at 300 K. The spectral distribution of the photoionization cross section of holes is obtained theoretically. It has been found that the magnitude of the photocapacitance quenching depends linearly on the intensity of the infrared ill… Show more

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Cited by 10 publications
(2 citation statements)
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“…22 It has been previously reported that group I metals such as Ag and Cu are fast-diffusing impurities in II-VI compounds, by this token, Ag + ions can occupy the Zn 2+ lattice sites in ZnS and can act as effective luminescent centers which are known to form the so-called blue centers. 23,24 Besides the contribution to optical property, the substitutional doping of Ag + in the ZnS NRs by replacing Zn 2+ could also account for the observed p-type characteristic of the NRs which will be discussed later on.…”
Section: Resultsmentioning
confidence: 99%
“…22 It has been previously reported that group I metals such as Ag and Cu are fast-diffusing impurities in II-VI compounds, by this token, Ag + ions can occupy the Zn 2+ lattice sites in ZnS and can act as effective luminescent centers which are known to form the so-called blue centers. 23,24 Besides the contribution to optical property, the substitutional doping of Ag + in the ZnS NRs by replacing Zn 2+ could also account for the observed p-type characteristic of the NRs which will be discussed later on.…”
Section: Resultsmentioning
confidence: 99%
“…Therefore, Cu + can occupy the Zn 2+ lattice sites in ZnS, which leads to the p-type characteristics of the NRs. 29,30 In order to assess the electrical properties of the ZnS : Cu NRs, back-gate FETs were constructed on the individual NRs. Fig.…”
Section: Resultsmentioning
confidence: 99%