A comparative study is carried out on two spectroscopic techniques employed to detect ultrafast absorption changes in the mid-infrared spectral range, namely direct multichannel detection via HgCdTe (MCT) photodiode arrays and the newly established technique of chirped-pulse upconversion (CPU). Whereas both methods are meanwhile individually used in a routine manner, we directly juxtapose their applicability in femtosecond pump-probe experiments based on 1 kHz shot-to-shot data acquisition. Additionally, we examine different phase-matching conditions in the CPU scheme for a given mid-infrared spectrum, thereby simultaneously detecting signals which are separated by more than 200 cm −1 . References and links 1. P. Stoutland, R. Dyer, and W. Woodruff, "Ultrafast infrared spectroscopy," Science 257, 1913-1917 (1992). 2. P. Hamm, S. Wiemann, M. Zurek, and W. Zinth, "Highly sensitive multichannel spectrometer for subpicosecond spectroscopy in the midinfrared," Opt. Lett. 19, 1642Lett. 19, -1644Lett. 19, (1994. 3. P. Hamm, R. A. Kaindl, and J. Stenger, "Noise suppression in femtosecond mid-infrared light sources," Opt. Lett. 25, 1798Lett. 25, -1800Lett. 25, (2000. 4. G. Cerullo and S. D. Silvestri, "Ultrafast optical parametric amplifiers," Rev. Sci. Instrum. 74, 1-18 (2003). 5. J. Moore, P. Hansen, and R. Hochstrasser, "A new method for picosecond time-resolved infrared spectroscopy: applications to CO photodissociation from iron porphyrins," Chem. Phys. Letters 138, 110-114 (1987). 6. T. P. Dougherty and E. J. Heilweil, "Dual-beam subpicosecond broadband infrared spectrometer," Opt. Lett. 19, 129-131 (1994). 7. M. Lim, T. Jackson, and P. Anfinrud, "Binding of CO to myoglobin from a heme pocket docking site to form nearly linear Fe-C-O," Science 269, 962-966 (1995). Current and future archive for earth and planetary atmosphere studies," J. Quant. Spectrosc. Radiat. Transf. 109, 1043-1059 (2008). 38. M. Kaucikas, J. Barber, and J. J. van Thor, "Polarization sensitive ultrafast mid-IR pump probe microspectrometer with diffraction limited spatial resolution," Opt.