Diode laser surface alloying process was used to the in-situ synthesis of TiC-reinforced composite surface layers on the ductile cast iron substrate. The obtained composite surface layers were investigated using optical and scanning electron microscopy, and XRD diffraction.It was found that the morphology and fraction of TiC phase is directly dependent upon both the concentration of titanium in the molten pool and also the solidification rate. With increasing titanium content, the fraction of TiC increases, whereas the fraction of cementite decreases. The TiC phase promotes a heterogeneous nucleation of primary austenite grains, what reduces a tendency of cracking in the alloyed layers.