Influence of solvent on the yield and chemical composition of liquid products of hydrothermal liquefaction of <i>Arthrospira platensis</i> as revealed by Fourier transform ion cyclotron resonance mass spectrometry

Vlaskin, Mikhail S.; Grigоrenko, A. V.; Kostyukevich, Yury; Nikolaev, Evgeny N.; Vladimirov, Gleb; Чернова, Н. І.; Киселева, С. В.; Popel, O. S.; Жук, А. З.

doi:10.1177/1469066718771209

Cited by 8 publications

(4 citation statements)

References 37 publications

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“…7 The biocrude concentration from HTL of Arthrospira platensis decreased in the following order: acetonitrile > DCM > hexane. 8 Watson et al 9 investigated the influence of three solvents on the biocrude yield and quality from HTL of algae with different biochemical compositions, and found that DCM gave the highest biocrude yield for Chlorella sp., toluene for Nannochloropsis sp., and acetone for Enteromorpha pr. The DCMrecovered biocrude had the largest higher heating value (HHV) for all three algae.…”

Section: ■ Introductionmentioning

confidence: 99%

110th Anniversary: Influence of Solvents on Biocrude from Hydrothermal Liquefaction of Soybean Oil, Soy Protein, Cellulose, Xylose, and Lignin, and Their Quinary Mixture

Liu

Zhang

et al. 2019

Ind. Eng. Chem. Res.

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We perform hydrothermal liquefaction (HTL) on five materials that model the major biochemical components in a wide array of biomass feedstocks: soybean oil, soy protein, cellulose, xylose, and lignin. The influence of different solvents (dichloromethane, acetone, methyl tert-butyl ether (MTBE)) on the yield, and the elemental content of the biocrude recovered from isothermal and fast HTL of these model compounds is determined. MTBE gives an ∼30% lower biocrude yield and about twice the solids yield, compared with dichloromethane (DCM) and acetone for both fast and isothermal HTL of a mixture of the five materials; however, the MTBE-recovered biocrude has the largest higher heating values (HHVs). The three solvents give similar biocrude yields for HTL of soybean oil and soy protein individually. Acetone recovers the highest biocrude yields from both isothermal and fast HTL of cellulose, xylose, or lignin individually, but the carbon content, hydrogen content, and HHV of the acetone-recovered biocrude are the lowest. The biocrude yields from the different feedstocks do not consistently vary monotonically with the normalized solvent polarity (E T N), which indicates that this property alone is not the controlling factor. Moreover, high yield and large HHV of the biocrude may not be available simultaneously with the pure solvents explored herein, which suggests there may be opportunities for solvent engineering in HTL product recovery. The biocrude yields from fast HTL of a quinary mixture of the model compounds are slightly higher than those from isothermal HTL conditions, which provides another example of the efficacy of fast HTL in valorizing biomass.

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Section: ■ Introductionmentioning

confidence: 99%

110th Anniversary: Influence of Solvents on Biocrude from Hydrothermal Liquefaction of Soybean Oil, Soy Protein, Cellulose, Xylose, and Lignin, and Their Quinary Mixture

Liu

Zhang

et al. 2019

Ind. Eng. Chem. Res.

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“…More details can be found in our previous publication. 52 Samples. Samples of Spirulina platensis were provided by colleagues from Moscow State University.…”

Section: ■ Methodsmentioning

confidence: 99%

Analysis of the Bio-oil Produced by the Hydrothermal Liquefaction of Biomass Using High-Resolution Mass Spectrometry and Isotope Exchange

et al. 2021

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Production of bio-oil by hydrothermal liquefaction of biomass is a promising way to achieve several sustainable development goals: renewable energy, proper waste treatment, reduction of greenhouse gas emissions, etc. For the wide application of bio-oil in industry and transport, it is important to study its molecular composition. However, the molecular composition of bio-oil is almost as complicated as that of natural petroleum, and despite the considerable amount of research, it is not fully understood. Here, we applied high-resolution mass spectrometry, collision induced dissociation, the isotope (H/D and 16 O/ 18 O) exchange approach, and other analytical techniques in order to obtain chemical information about individual molecules of bio-oil. We proved the presence of different nitrogen functionalities including quaternary nitrogen in the bio-oil. Analyzing MS/ MS spectra of individual compounds, we proposed possible structures of individual molecules of bio-oil.

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“…ESI FT-ICR MS showed great advantages in the molecular characterization of bio-crudes and has been widely used for the analysis of pyrolysis bio-crudes from various biomass sources. For example, pyrolysis products from pine pellet and peanut hull, red pine, , willow, loblolly pine, , oak, ,− mixed conifer and scotch broom, lignocellulosic biomass of hardwood, miscanthus, softwood and wheat straw; ,,, invasive freshwater plants, cedar chips, pine wood and sugar cane bagasse, Spirulina platensis , conifer sawdust, defatted cottonseed, rice husk, , sawdust, cellulose, hemicellulose(xylan) and lignin, domestic sewage sludge; hydrothermal liquefaction products from sweet sorghum stalk, , organic waste, isolated cuticle of Agave americana and Capsicum annuum , microcrystalline cellulose, xylan and industrial lignin, kitchen waste, food waste (meat, cheese and fruits), waste sedum plumbizincicola, and microalgae ( Arthrospira platensis and Spirulina platensis ).…”

Section: Characterization Of Alternative Fuelsmentioning

confidence: 99%

“…Vlaskin et al 307 HTL of Arthrospira platensis using different solvents has been determined. The compounds containing two nitrogen atoms and compounds containing four oxygen atoms are dominant in (+)ESI and (−)ESI, respectively.…”

Section: Characterization Of Alternative Fuelsmentioning

confidence: 99%

Molecular Characterization of Fossil and Alternative Fuels Using Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry: Recent Advances and Perspectives

et al. 2021

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Molecular composition analysis of petroleum and alternative fuels has been considered as one of the greatest challenges in analytical chemistry. The rapid development of Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) has provided an opportunity to solve this problem. High mass resolution power and mass accuracy enable the separation of isobaric compounds in a complex mixture and assignment of their molecular composition. The combination of electrospray ionization (ESI) with FT-ICR MS achieves direct analysis of polar compounds in petroleum even if they are in trace amounts in the complex matrix. FT-ICR MS has made a great contribution to the chemical understanding of petroleum and alternative fuels; the relevant application is sometimes called “petroleomic analysis”. Hundreds of journal articles have been published over the past two decades using FT-ICR MS instruments to study the molecular composition of petroleum and alternative fuels, in which most of them used ESI as the ionization source. This review will present an overview of the studies regarding the petroleomic characterization of fossil and alternative fuels by FT-ICR MS coupled with ESI and a critical review of their main findings relevant to the chemical composition. Special features of this review are (1) covering the entire historical period; (2) focusing on ESI ionization; (3) a systematic review of the composition of almost all the components and compound classes, including but not limited to petroleum, coal-derived liquids, biofuels, and their distillates; asphaltenes, heavy residues, interfacial active substances; hydrocarbons and heteroatoms; and polar and nonpolar compounds. In addition, the challenges and further research directions will be proposed. This review focuses on the advances enabled by ultrahigh resolving power FT-ICR MS in a tribute to Professor Alan G. Marshall.

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Influence of solvent on the yield and chemical composition of liquid products of hydrothermal liquefaction of Arthrospira platensis as revealed by Fourier transform ion cyclotron resonance mass spectrometry

Cited by 8 publications

References 37 publications

110th Anniversary: Influence of Solvents on Biocrude from Hydrothermal Liquefaction of Soybean Oil, Soy Protein, Cellulose, Xylose, and Lignin, and Their Quinary Mixture

110th Anniversary: Influence of Solvents on Biocrude from Hydrothermal Liquefaction of Soybean Oil, Soy Protein, Cellulose, Xylose, and Lignin, and Their Quinary Mixture

Analysis of the Bio-oil Produced by the Hydrothermal Liquefaction of Biomass Using High-Resolution Mass Spectrometry and Isotope Exchange

Molecular Characterization of Fossil and Alternative Fuels Using Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry: Recent Advances and Perspectives

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