Abstract:Electrocaloric effects due to entropy change and dipole coupling upon electric field in second-order phase transition (tetragonal-cubic) ferroelectrics are investigated by a three-dimensional Devonshire's theory and statistic method. In diabatic condition, increase in vibration entropy to heat the ferroelectric is due to decreases in polarization entropy and configuration entropy of dipole reorientation in the specific directions. Coupling effect originated from the reorientation of dipoles accompany with elec… Show more
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