Abstract:Titanium dioxide (TiO2) shows a great interest in solar cell application due to its morphology and crystalline structure. Moreover, it is an affordable compound that could make solar cells more economical than traditional silicon solar cells. In this study, one-step hydrothermal method is demonstrated to synthesis TiO2 nanorods/nanoflowers morphology on different hydrothermal reaction temperature. Increasing the reaction temperature could influence the formation of highly crystalline rutile phase of titania th… Show more
“…However, these peaks low and weak intensity, which indicates that Cu2O did not fully grow on the TiO2 nanorods layer. The crystallite size of Cu2O phase was calculated by Scherrer equation [20]. It can be observed that the crystallite sizes of Cu2O increased when the deposition time increased as proven by the FWHM values as shown in Table 1.…”
This study focused on the copper (I) oxide (Cu2O) that serves as an absorber layer, owing to its excellent optical properties, while titanium dioxide (TiO2) is a well-known material that has superior properties in solar cell development. In this work, the TiO2 nanorods layer was synthesised on a fluorine-doped tin oxide (FTO) glass substrate by a facile hydrothermal method followed by stacking the Cu2O layer using a low-cost electrodeposition method at different deposition times. Prior to deposition, a cyclic voltammetry (CV) measurement was performed, and the result showed that Cu2O films were successfully grown on the TiO2 nanorods layer with high uniformity. The crystallinity of the Cu2O/TiO2 film was increased when the deposition time was elevated. The strongest diffraction peak was detected in the sample deposited for 90 minutes. FE-SEM images revealed the formation of the pyramidal structure of Cu2O on the TiO2nanorod layer. The optical properties showed that the samples deposited at 60 minutes and above were red-shifted, with the estimated bandgap being slightly decreased when extending the deposition time. Meanwhile, the resistivity and sheet resistance of the as-prepared samples were increased. The performance of the solar cell was investigated, and the power energy conversion was slightly increased to 0.0267% for the heterojunction sample deposited at 90 minutes. Doi: 10.28991/HEF-2021-02-04-02 Full Text: PDF
“…However, these peaks low and weak intensity, which indicates that Cu2O did not fully grow on the TiO2 nanorods layer. The crystallite size of Cu2O phase was calculated by Scherrer equation [20]. It can be observed that the crystallite sizes of Cu2O increased when the deposition time increased as proven by the FWHM values as shown in Table 1.…”
This study focused on the copper (I) oxide (Cu2O) that serves as an absorber layer, owing to its excellent optical properties, while titanium dioxide (TiO2) is a well-known material that has superior properties in solar cell development. In this work, the TiO2 nanorods layer was synthesised on a fluorine-doped tin oxide (FTO) glass substrate by a facile hydrothermal method followed by stacking the Cu2O layer using a low-cost electrodeposition method at different deposition times. Prior to deposition, a cyclic voltammetry (CV) measurement was performed, and the result showed that Cu2O films were successfully grown on the TiO2 nanorods layer with high uniformity. The crystallinity of the Cu2O/TiO2 film was increased when the deposition time was elevated. The strongest diffraction peak was detected in the sample deposited for 90 minutes. FE-SEM images revealed the formation of the pyramidal structure of Cu2O on the TiO2nanorod layer. The optical properties showed that the samples deposited at 60 minutes and above were red-shifted, with the estimated bandgap being slightly decreased when extending the deposition time. Meanwhile, the resistivity and sheet resistance of the as-prepared samples were increased. The performance of the solar cell was investigated, and the power energy conversion was slightly increased to 0.0267% for the heterojunction sample deposited at 90 minutes. Doi: 10.28991/HEF-2021-02-04-02 Full Text: PDF
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