Influence of carbon nanotubes on the properties of biopolyol based polyurethane foams

Abstract

Biopolyols were obtained from liquefaction of sugarcane bagasse and rice husk. Acid and hydroxyl numbers were determined for estimating the polyol value of the liquid products. These prepared biopolyols were mixed with the commercial polyol for the preparation of polyurethane foam (PU). To study the effects of biopolyol on properties of PU foam, various ratios of biopolyol to commercial polyol were used. It was observed that the density and foaming time of the PU foam increases with the increase in biopolyol content. The calculated Isocyanate index showed that sugarcane bagasse polyol can be used to make flexible foam and that rice husk can be used to make rigid foam. Foaming times and full rise times increased with increase in the biopolyol content. The Fourier-transform infrared spectroscopy (FTIR) spectra of prepared foams showed the characteristic peaks related to PU foam. The morphological studies were carried out using scanning electron microscopy (SEM). Thermal conductivity tests proved that the synthesized PU foams can be used as insulating materials. Further, PU foams were also prepared with the incorporation of carbon nanotubes (CNTs) in the polyol. The densities, thermal conductivities and SEM analysis of PU foams with and without carbon nanotubes were compared.

A study on coconut fatty acid diethanolamide-based polyurethane foams

“…9,10 In the production process of polyurethane foam, according to different application requirements, the polyol, isocyanate and catalyst types can be adjusted to produce different properties of foam, such as high temperature resistant foam, ame retardant foam, acoustic insulation foam, high resilience foam, etc. 11,12 In the 21st century, with the rapid development of global industrialization, petrochemical resources are getting depleted, and problems such as serious petroleum-based pollution and difficulties in waste degradation have seriously affected the development of polyurethane industry. [13][14][15][16] Therefore, it is particularly important to nd suitable alternatives for petroleum-based materials.…”

“…9,10 In the production process of polyurethane foam, according to different application requirements, the polyol, isocyanate and catalyst types can be adjusted to produce different properties of foam, such as high temperature resistant foam, flame retardant foam, acoustic insulation foam, high resilience foam, etc. 11,12…”