In this paper, based on the anisotropic nature of hydrogen (H 2 ) etching on GaN, we describe a new approach to the removal of threading dislocations in GaN layers. The top surfaces of c-plane (Ga-face) and a-plane GaNs are considered stable in H 2 ; therefore, H 2 etches only crystal imperfections such as dislocation and basal plane stacking fault (BSF) sites. We used H 2 to etch undoped c-plane GaN, n-type c-plane GaN, a-plane GaN, and an InGaN/GaN multiple quantum well structure. Several examinations were performed, indicating deep cavities on the c-plane GaN samples after H 2 etching; furthermore, gorge-like grooves were observed on the a-plane GaN samples. The deep cavities on the c-plane GaN were considered the etched dislocation sites, and the gorge-like grooves on the a-plane GaN were considered the etched BSF sites. Photoluminescence measurements were performed and the results indicated that the H 2 -etched samples demonstrate superior optoelectronic properties, probably because of the elimination of dislocations.