In Vitro Analysis of AHPlus and MM-Seal by ESR and Thermoanalytical Methods

Ceylan, Yusuf; Usta, Ayhan; Usta, K.; Çobankara, Funda Kont; Yıldırım, Cihan; Birey, Mehmet

doi:10.12693/aphyspola.128.b-479

Cited by 5 publications

(3 citation statements)

References 36 publications

(32 reference statements)

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“…In recent years, electron paramagnetic resonance (EPR) technique has been widely used for characterization of various materials . Researchers have investigated compounds containing Ag and Br by using EPR method.…”

Section: Introductionsupporting

confidence: 87%

Identification of radical structures on 1-pentamethylbenzyl-3-ethylimidazoliumsilver(I)bromide and 1,3-bis(pentamethylbenzyl)-4,5-dimethylbenzimidazoliumsilver(I)bromide exposed to gamma rays: an EPR study

et al. 2016

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1-Pentamethylbenzyl-3-ethylimidazoliumsilver(I)bromide and 1,3-bis(pentamethylbenzyl)-4,5dimethylbenzimidazoliumsilver(I)bromide and their Ag complexes were synthesized and their polycrystal forms were produced by recrystallization in dichloromethane/Et O solvent system. Structural determinations were carried out by H NMR and C NMR with a Varian 400 NMR system using tetramethylsilane as internal standard and CDCl as solvent. The disappearance of acidic N-heterocyclic carbene proton showed the formation of Ag(I) complexes. Also, elemental analyses were carried out. Electron paramagnetic resonance (EPR) measurements were performed to determine the formed radical structure on the samples irradiated at the room temperature for 72 h by using Co-source with dose rate of 0.680 kGy. The EPR measurements were carried out in the temperature range of 200 K-450 K. Identical radicals were determined on the irradiated compounds. It was observed that the shapes of the spectra of the samples were independent of the temperature but, the resonance line intensities changed linearly with the temperature. Also, it was detected that the free radical on the 1-pentamethylbenzyl-3-ethylimidazoliumsilver(I)bromide is not stable compared to that on the 1,3-bis(pentamethylbenzyl)-4,5dimethylbenzimidazoliumsilver(I)bromide. Copyright © 2016 John Wiley& Sons, Ltd.

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Section: Introductionsupporting

confidence: 87%

Identification of radical structures on 1-pentamethylbenzyl-3-ethylimidazoliumsilver(I)bromide and 1,3-bis(pentamethylbenzyl)-4,5-dimethylbenzimidazoliumsilver(I)bromide exposed to gamma rays: an EPR study

et al. 2016

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“…They will be able to earn time and make more qualified evaluations. Studies on decision making are for specifically processes regarding ranking or selecting the best alternative according to cognitive information [16][17][18][19][20].…”

Section: Introductionmentioning

confidence: 99%

A Model Proposal for Wall Material Selection Decisions by Using Analytic Hierarchy Process (AHP)

Uğur

Baykan²

2017

Acta Phys. Pol. A

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Analytical hierarchy process, developed by Saaty, is a multi-criteria decision making method. It creates a hierarchy using the goal, decision criteria and decision alternatives, and sorts the various alternatives according to their relative importance. The aim in AHP is to choose the most suitable and important alternative, by making an arrangement from the most important to the least. In this study, a real life material selection application in a hotel building is described by using AHP method. Wall materials such as brick blocks, pumice concrete block, sand autoclaved aerated concrete blocks are decision alternatives and mechanical properties, physical properties, ease of application and costs of these materials are the decision factors. The analysis was performed based on the opinion of an expert and the most suitable alternative is selected. Also, it is concluded that the order related to the alternatives is reliable for the decision markers. Thus, a decision supporting method for a construction company using AHP applications is developed.

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“…Therefore, it is important to identify radical structures produced by irradiation. EPR is a powerful spectroscopic method for detecting radicals in the materials [7][8][9][10][11][12][13][14][15][16][17][18]. In this study, Calix [4]arene, labeled calix [4]arene (1), and 25,27-di(4-nitrobenzyl)-26,28-dihydroxycalix [4]arene, labeled calix [4]arene(2), were exposed to gamma rays and then radical structures of these calix [4]arenes were evaluated by EPR method.…”

Section: Introductionmentioning

confidence: 99%

Comparative Study of Influences of Gamma Rays on Calix[4]Arene and 25,27-di(4-Nitrobenzyl)-26,28-Dihydroxycalix[4]Arene: EPR Study

et al. 2017

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In the present study, calix [4]arene and its derivate 25,27-di(4-nitrobenzyl)-26,28-dihydroxycalix[4]arene were irradiated for 72 hours by 60 Co gamma rays at dose rate of 0.720 kGy/h. These irradiated samples were analyzed by EPR method and it was found that one type of radical was produced in calix[4]arene, and two type of radicals were produced in 25,27-di(4-nitrobenzyl)-26,28-dihydroxycalix[4]arene. The measurements were performed in the temperature range of 273-400 K using x-band EPR spectrometer. It was observed that the spectra, obtained from two samples, have very weak temperature dependence. Hyperfine and g parameters were calculated for two samples.

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In Vitro Analysis of AHPlus and MM-Seal by ESR and Thermoanalytical Methods

Cited by 5 publications

References 36 publications

Identification of radical structures on 1-pentamethylbenzyl-3-ethylimidazoliumsilver(I)bromide and 1,3-bis(pentamethylbenzyl)-4,5-dimethylbenzimidazoliumsilver(I)bromide exposed to gamma rays: an EPR study

Identification of radical structures on 1-pentamethylbenzyl-3-ethylimidazoliumsilver(I)bromide and 1,3-bis(pentamethylbenzyl)-4,5-dimethylbenzimidazoliumsilver(I)bromide exposed to gamma rays: an EPR study

A Model Proposal for Wall Material Selection Decisions by Using Analytic Hierarchy Process (AHP)

Comparative Study of Influences of Gamma Rays on Calix[4]Arene and 25,27-di(4-Nitrobenzyl)-26,28-Dihydroxycalix[4]Arene: EPR Study

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