“…Since Ovshinsky proposed the occurrence of the threshold switching phenomenon in Ge 10 Si 12 As 30 Te 48 in the 1960s, 15 numerous OTS materials have been discovered and studied, including Te-, Se- and S-based chalcogenides. 16–20 Elements such as N, Si, As, Sb, and C are doped into chalcogenide materials to optimize the performance of OTS devices, 21–24 impacting the parameters such as the on/off ratio, on-state current, endurance, threshold voltage, and thermal stability; this, however, inevitably results in the increase in material complexity. To satisfy the stringent performance requirements of the industry, OTS material systems are predominantly ternary, quaternary, or even quinary in composition and often contain toxic elements, leading to environmental unfriendliness and industrial incompatibility.…”