A new
process was proposed to reduce fine particle emissions in coal-fired
flue gases via the condensation of SO3 and water vapor.
In this new process, hot atomized water was sprayed before the electrostatic
precipitator (ESP) system to decrease the flue gas temperature and
increase the flue gas humidity, causing the flue gas temperature to
drop below the acid dew point; thus, SO3 would condense
on the particle surfaces ahead of the ESP, which would enhance the
fine particle removal efficiency of the ESP. Then, a fluoroplastic
heat exchanger was located between the ESP and the wet flue gas desulfurization
(WFGD) system to make the WFGD inlet flue gas temperature decrease
further at a high humidity, leading to the condensation of water vapor
on the particle surfaces in the desulfurization scrubber, which would
improve the removal efficiency of the WFGD. The feasibility of this
new process was analyzed by numerical calculation, and the results
showed that the new process was feasible for the original flue gas
with high SO3 concentrations, high temperature, and high
humidity. The effectiveness of this new process under typical operating
conditions was also presented. Furthermore, the influence of several
main parameters, such as the SO3 concentration of original
flue gas, the temperature drop of flue gas before the ESP, and the
temperature of flue gas at the WFGD inlet, were also investigated.
The results indicated that the fine particle emissions in the final
exhausted flue gas would be reduced by 50–70% with this new
process.