Improvement of the Li-ion conductivity and air stability of the Ta-doped Li7La3Zr2O12 electrolyte via Ga co-doping and its application in Li–S batteries

Ma, Kai; Chen, Bowen; Li, Cheng-Xin; Thangadurai, Venkataraman

doi:10.1039/d3ta06229e

J. Mater. Chem. A

2024

DOI: 10.1039/d3ta06229e

|View full text |Cite

Improvement of the Li-ion conductivity and air stability of the Ta-doped Li₇La₃Zr₂O₁₂ electrolyte via Ga co-doping and its application in Li–S batteries

Kai Ma,

Bowen Chen,

Cheng-Xin Li

et al.

Abstract: The garnet-type solid electrolyte Li7La3Zr2O12 (LLZO) has emerged as a promising candidate for all-solid-state lithium-ion batteries (ASSLBs) due to its exceptional performance. However, it currently faces challenges related to low...

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article3

Relationship

Self Cite0

Independent3

Authors

Journals

Cited by 3 publications

References 70 publications

(125 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

Accelerating the Development of LLZO in Solid‐State Batteries Toward Commercialization: A Comprehensive Review

Wang,

Chen,

Jiang

et al. 2024

Small

View full text Add to dashboard Cite

Solid‐state batteries (SSBs) are under development as high‐priority technologies for safe and energy‐dense next‐generation electrochemical energy storage systems operating over a wide temperature range. Solid‐state electrolytes (SSEs) exhibit high thermal stability and, in some cases, the ability to prevent dendrite growth through a physical barrier, and compatibility with the “holy grail” metallic lithium. These unique advantages of SSEs have spurred significant research interests during the last decade. Garnet‐type SSEs, that is, Li7La3Zr2O12 (LLZO), are intensively investigated due to their high Li‐ion conductivity and exceptional chemical and electrochemical stability against lithium metal anodes. However, poor interfacial contact with cathode materials, undesirable lithium plating along grain boundaries, and moisture‐induced chemical degradation greatly hinder the practical implementation of LLZO‐based SSEs for SSBs. In this review, the recent advances in synthesis methods, modification strategies, corresponding mechanisms, and applications of garnet‐based SSEs in SSBs are critically summarized. Furthermore, a comprehensive evaluation of the challenges and development trends of LLZO‐based electrolytes in practical applications is presented to accelerate their development for high‐performance SSBs.

show abstract

Accelerating the Development of LLZO in Solid‐State Batteries Toward Commercialization: A Comprehensive Review

Wang,

Chen,

Jiang

et al. 2024

Small

View full text Add to dashboard Cite

show abstract

Challenges to Li7La3Zr2O12 system electrolyte and the modification: From powder to ceramic

Xiao,

Yang,

Wang

et al. 2024

Journal of Alloys and Compounds

View full text Add to dashboard Cite

Reasonable design a high-entropy garnet-type solid electrolyte for all-solid-state lithium batteries

Yu,

Li,

Luo

et al. 2024

Journal of Energy Chemistry

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

hi@scite.ai

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Improvement of the Li-ion conductivity and air stability of the Ta-doped Li₇La₃Zr₂O₁₂ electrolyte via Ga co-doping and its application in Li–S batteries

Abstract: The garnet-type solid electrolyte Li7La3Zr2O12 (LLZO) has emerged as a promising candidate for all-solid-state lithium-ion batteries (ASSLBs) due to its exceptional performance. However, it currently faces challenges related to low...

Cited by 3 publications

References 70 publications

Accelerating the Development of LLZO in Solid‐State Batteries Toward Commercialization: A Comprehensive Review

Accelerating the Development of LLZO in Solid‐State Batteries Toward Commercialization: A Comprehensive Review

Challenges to Li7La3Zr2O12 system electrolyte and the modification: From powder to ceramic

Reasonable design a high-entropy garnet-type solid electrolyte for all-solid-state lithium batteries

Contact Info

Product

Resources

About