Poly(hydroxyurethane)s
(PHUs) are synthesized via non-isocyanate
approaches and could be the potential alternatives of conventional
polyurethanes. It is of importance to investigate the structure–property
relationship of PHUs. In this work, we investigated the PHU nanocomposites
containing multiwalled carbon nanotubes (CNTs). First, CNTs were functionalized
with poly(acryloyl carbonate), a polymer bearing 6-membered cyclic
carbonate groups (denoted PA6CC) via the surface
reversible addition–fragmentation chain transfer polymerization
approach. Thereafter, the PA6CC-grafted CNTs were dispersed in the
mixtures of 6-membered bicyclic carbonate (6BCC) and tris(2-aminoethyl)amine.
By initiating the curing reaction, the nanocomposites were successfully
obtained with the content of CNTs up to 11 wt %. The morphological
investigation showed that CNTs were well dispersed in the PHU matrix;
the CNTs preserved good integrity. The PHU nanocomposites displayed
a series of improved thermomechanical properties in terms of glass
transition temperatures (T
g’s),
tensile mechanical properties, and thermal conductivity. Compared
to plain PHU thermoset, the PHU nanocomposites possessed enhanced
dielectric constants and low dielectric loss. Owing to the introduction
of CNTs, the nanocomposites displayed improved shape memory properties.
It was found that the nanocomposites preserved reprocessing properties
at elevated temperatures as plain PHU. The reprocessing properties
bestowed the shape memory materials with reprograming ability of original
shapes.